期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 364, 期 24, 页码 4384-4391出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202201143
关键词
Visible-light photocatalysis; Radical; Copper catalysis; N-Heterocycles
资金
- National Natural Science Foundation of China
- Scientific Research Foundation of Qingdao University of Science and Technology
- [22271170]
In this manuscript, a radical type ring-opening of sulfonium salts with heteroarenes under visible light conditions is reported. This method does not rely on noble metal photocatalysts or stoichiometric amounts of external oxidants, making it promising for the synthesis of organosulfur compounds and bioactive molecules. The developed photocatalytic system could inspire further applications of sulfonium salts in C(sp(3))-C(sp(2)) bond forming reactions.
In this manuscript, we report a radical type ring-opening of sulfonium salts with heteroarenes under visible light conditions. This developed method does not require noble metal photocatalysts, or stoichiometric amount of external oxidants, and has a application prospect in the synthesis of organosulfur compounds and bioactive molecules. This radical type ring-opening photocatalytic system could inspire further applications of sulfonium salts in C(sp(3))-C(sp(2)) bond forming reactions.
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