☆ 4.8 Review

On the Road to the Frontiers of Lithium-Ion Batteries: A Review and Outlook of Graphene Anodes

ADVANCED MATERIALS (2023)

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Summary: This article reviews the recent progress in the fabrication and application of 3D porous graphene with designable microstructures, chemistries, and properties for energy storage and conversion. The 3D graphene, synthesized through template-based and template-free methods, retains the highly conductive and mechanically robust properties of 2D graphene while offering new functionalities and opportunities.

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Summary: The study focuses on the synthesis of graphene foam as anode material using the CVD method, and its stable performance in coin-cell lithium-ion batteries with a high specific capacity at 0.1 C. The research shows that the GF-anode exhibits stable performance in charge-discharge cycles with high specific capacity.

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Summary: A new strategy for designing Pt-alternative electrocatalysts with outstanding electrochemical performances for high-efficiency water splitting and other applications was proposed by employing an in-situ interface engineering strategy to construct high-performance and cost effective electrocatalysts comprising WC/tungsten phosphide (WP) heterostructures anchored on N,P-codoped carbon (WC/WP@NPC) via a one-step pyrolysis. The synergistic effect of crystal structure compatibility, electron-rich property, fast electron transport, and structural stability led to outstanding HER performances of the catalyst in acidic and alkaline media.

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Summary: In order to make electric vehicles more viable for the general population, rechargeable batteries need to support rapid charging and increase energy density. This study introduces graphite oxide frameworks with enlarged interlayer spacing through a solvothermal reaction, resulting in ultrafast charging properties.

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Summary: The research focuses on improving lithium-ion battery technology by developing high-performance electrode materials, with graphene and hydrogenated graphene showing promising potential. The study demonstrates the capabilities of these materials in terms of specific capacity and charge/discharge rates. It also explores the diffusion mechanisms of lithium in graphene-based electrodes and proposes a novel charge storage mechanism. The feasibility of applying graphene and hydrogenated graphene anodes to full cells is also evaluated.

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Anomalous Self-Optimizing Microporous Graphene-Based Lithium-ion Battery Anode from Laser Activation of Small Organic Molecules

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Soft Template-Assisted Fabrication of Mesoporous Graphenes for High-Performance Energy Storage Systems

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Review Chemistry, Multidisciplinary

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Hybrid carbon nanotube and graphene nanostructures for lithium ion battery anodes

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NANO ENERGY (2014)

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Porous graphene networks as high performance anode materials for lithium ion batteries

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JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

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JOURNAL OF POWER SOURCES (2013)

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Free-standing graphene-carbon nanotube hybrid papers used as current collector and binder free anodes for lithium ion batteries

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Yang-Xin Yu

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

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The examination of graphene oxide for rechargeable lithium storage as a novel cathode material

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Chemical vapor deposition derived flexible graphene paper and its application as high performance anodes for lithium rechargeable batteries

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Ultrathin rechargeable all-solid-state batteries based on monolayer graphene

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Randomly stacked holey graphene anodes for lithium ion batteries with enhanced electrochemical performance

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JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Nitrogen-self-doped graphene as a high capacity anode material for lithium-ion batteries

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JOURNAL OF MATERIALS CHEMISTRY A (2013)

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Photothermally Reduced Graphene as High-Power Anodes for Lithium-Ion Batteries

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Folded Structured Graphene Paper for High Performance Electrode Materials

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Reduced graphene oxide paper by supercritical ethanol treatment and its electrochemical properties

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Chemical-free synthesis of graphene-carbon nanotube hybrid materials for reversible lithium storage in lithium-ion batteries

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In situ transmission electron microscopy of electrochemical lithiation, delithiation and deformation of individual graphene nanoribbons

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CARBON (2012)

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CHEMICAL COMMUNICATIONS (2012)

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Benzoxazole and benzimidazole heterocycle-grafted graphene for high-performance supercapacitor electrodes

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Composites of chemically-reduced graphene oxide sheets and carbon nanospheres with three-dimensional network structure as anode materials for lithium ion batteries

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Synthesis of graphene-multiwalled carbon nanotubes hybrid nanostructure by strengthened electrostatic interaction and its lithium ion battery application

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JOURNAL OF MATERIALS CHEMISTRY (2012)

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Nitrogen-doped graphene nanosheets as anode materials for lithium ion batteries: a first-principles study

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JOURNAL OF MATERIALS CHEMISTRY (2012)

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Li Absorption and Intercalation in Single Layer Graphene and Few Layer Graphene by First Principles

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MATERIALS CHEMISTRY AND PHYSICS (2012)

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PHYSICAL REVIEW B (2012)

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Edge-carboxylated graphene nanosheets via ball milling

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PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2012)

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Microwave-assisted synthesis of reduced graphene oxide-carbon nanotube composites as negative electrode materials for lithium ion batteries

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Density functional theory prediction for diffusion of lithium on boron-doped graphene surface

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Microspheres composed of multilayer graphene as anode material for lithium-ion batteries

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Direct preparation of 1-PSA modified graphene nanosheets by supercritical fluidic exfoliation and its electrochemical properties

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Nitrogen-doped graphene nanosheets with excellent lithium storage properties

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Enhanced Li capacity at high lithiation potentials in graphene oxide

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Lithium adsorption on armchair graphene nanoribbons

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First-principles studies on doped graphene as anode materials in lithium-ion batteries

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Vertically Aligned Carbon Nanotubes Grown on Graphene Paper as Electrodes in Lithium-Ion Batteries and Dye-Sensitized Solar Cells

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Nanographene-Constructed Hollow Carbon Spheres and Their Favorable Electroactivity with Respect to Lithium Storage

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Graphene and Graphene Oxide: Synthesis, Properties, and Applications

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

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Graphene-based materials in electrochemistry

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CHEMICAL SOCIETY REVIEWS (2010)

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Hollow graphene oxide spheres self-assembled by W/O emulsion

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Novel properties of graphene nanoribbons: a review

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Chemical Functionalization of Graphene Nanoribbons

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JOURNAL OF NANOMATERIALS (2010)

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Non-Annealed Graphene Paper as a Binder-Free Anode for Lithium-Ion Batteries

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Effects of Off-Stoichiometry of LiC6 on the Lithium Diffusion Mechanism and Diffusivity by First Principles Calculations

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Lithium Diffusion in Graphitic Carbon

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JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2010)

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Enhanced Electrochemical Lithium Storage by Graphene Nanoribbons

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Edge Effects on the Characteristics of Li Diffusion in Graphene

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NANO LETTERS (2010)

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The Interaction of Li+ with Single-Layer and Few-Layer Graphene

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NANO LETTERS (2010)

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Roll-to-roll production of 30-inch graphene films for transparent electrodes

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Functionalization of Porous Carbon Materials with Designed Pore Architecture

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Self-Assembled Free-Standing Graphite Oxide Membrane

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First-principles study on the enhancement of lithium storage capacity in boron doped graphene

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APPLIED PHYSICS LETTERS (2009)

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Rapid, Facile Microwave-Solvothermal Synthesis of Graphene Nanosheets and Their Polyaniline Nanocomposites for Energy Strorage

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Li Storage Properties of Disordered Graphene Nanosheets

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CHEMISTRY OF MATERIALS (2009)

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Electrochemical Properties of Graphene Paper Electrodes Used in Lithium Batteries

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CHEMISTRY OF MATERIALS (2009)

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Lithium adsorption on zigzag graphene nanoribbons

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JOURNAL OF APPLIED PHYSICS (2009)

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Highly conductive paper for energy-storage devices

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PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2009)

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Large reversible Li storage of graphene nanosheet families for use in rechargeable lithium ion batteries

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NANO LETTERS (2008)

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Highly conducting graphene sheets and Langmuir-Blodgett films

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NATURE NANOTECHNOLOGY (2008)

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Processable aqueous dispersions of graphene nanosheets

Dan Li et al.

NATURE NANOTECHNOLOGY (2008)

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Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material

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NATURE NANOTECHNOLOGY (2008)

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Electronic transport properties of individual chemically reduced graphene oxide sheets

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NANO LETTERS (2007)

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Preparation and characterization of graphene oxide paper

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NATURE (2007)

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The structure of suspended graphene sheets

Jannik C. Meyer et al.

NATURE (2007)

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Intercalation chemistry of graphite-like layered material BC6N for anode of Li ion battery

M. Kawaguchi et al.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2006)

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Article Multidisciplinary Sciences

Electric field effect in atomically thin carbon films

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SCIENCE (2004)

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