期刊
ADVANCED FUNCTIONAL MATERIALS
卷 33, 期 16, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202215055
关键词
dynamic covalent bonds; mechanochromism; photonic vitrimers; self-healing; thermal management devices
This paper reports the design of mechanochromic self-healing thermal management devices based on photonic vitrimer. A series of new photonic vitrimers were prepared by dynamic disulfide covalent bond and PS@SiO2 photonic crystals. The resulting photonic vitrimer exhibits bright structural colors, large tensile strain, high mechanical strength, and self-healing ability. Taking advantage of these features, a novel mechanochromic flexible wireless thermal management (MFW) device was developed, which shows promising applications in wearable electronics, vitro physiotherapy, and personal heating.
Flexible self-healing thermal management devices are increasingly in demand due to their high flexibility, low driving voltage, and excellent stability of thermal property. In this paper, the design of mechanochromic self-healing thermal management devices is reported based on photonic vitrimer through self-healing dynamic covalent bond. A series of new photonic vitrimers i first prepared by dynamic disulfide covalent bond and PS@SiO2 photonic crystals. The resulting photonic vitrimer exhibits bright structural colors, large tensile strain (>1000%), high mechanical strength (>10 MPa) and self-healing ability (>95% efficiency). More importantly, the structural color remains constant after 10000 stretching/releasing cycles, demonstrating excellent mechanical stability, creep-resistance, and durability. Taking advantage of the above features, a novel mechanochromic flexible wireless thermal management (MFW) device is developed by semi-embedding the photonic vitrimer in a thermally conductive carbon nanotube film and then integrating it with a Bluetooth module and a control chip. Interestingly, the MFW device exhibits mechanochromic property, fast thermal response, low driving voltage (103 degrees C, at 3 V), and precise temperature control. Notably, the device even remains electrothermal performance (105 degrees C) after self-healing. This work provides new insight into the self-healing photonic materials, and the device shows promising applications in wearable electronics, vitro physiotherapy, and personal heating.
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