☆ 4.8 Review

Deciphering Electrolyte Selection for Electrochemical Reduction of Carbon Dioxide and Nitrogen to High-Value-Added Chemicals

ADVANCED FUNCTIONAL MATERIALS (2023)

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Article Engineering, Environmental

A superaerophilic gas diffusion electrode enabling facilitated nitrogen feeding through hierarchical micro/nano channels for efficient ambient synthesis of ammonia

Yanzheng He et al.

Summary: Electroreduction of nitrogen offers opportunities for meeting carbon neutrality in the synthetic ammonia industry. The challenge lies in improving catalyst activity and maximizing three-phase reaction region within the working electrode. To address this, a superaerophilic electrode with hierarchical gas diffusion channels is designed to enhance nitrogen-catalyst contact. This electrode increases Faradaic efficiency by nearly 6-fold compared to conventional electrodes, approaching the target set by the U.S. Department of Energy (90%).

CHEMICAL ENGINEERING JOURNAL (2023)

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Article Engineering, Environmental

High performance carbon dioxide electroreduction in ionic liquids with in situ shell-isolated nanoparticle-enhanced Raman spectroscopy

Ye Hu et al.

Summary: Ionic liquids (ILs) have advantages in improving the Faradaic efficiency (FE) and current density of electrochemical CO2 reduction (ECR). In this study, in situ shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS) was used to investigate the ECR process on nickel foam (NF) in imidazolium ILs. The results showed that 1-Butyl-3-methylimidazolium chloride (BmimCl) exhibited the best performance with a high FE of CO (94.6%) and a considerable current density (72 mA cm-2). The study provided promising insights into the CO2 electroreduction mechanism in ILs.

CHEMICAL ENGINEERING JOURNAL (2023)

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Review Chemistry, Inorganic & Nuclear

Covalent organic frameworks towards photocatalytic applications: Design principles, achievements, and opportunities

Sisi Liu et al.

Summary: COFs, as a subclass of porous framework materials, possess permanent porosity, long-range order, and rigid backbones, offering a significant material platform for addressing global energy and environmental crisis. With the rapid development of various fields, COF-based photocatalysis has achieved remarkable progress and shown immense potential in applications such as gas storage, energy conversion, and organic transformation.

COORDINATION CHEMISTRY REVIEWS (2023)

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Article Chemistry, Multidisciplinary

Interfacial Microextraction Boosting Nitrogen Feed for Efficient Ambient Ammonia Synthesis in Aqueous Electrolyte

Xiaowei Shen et al.

Summary: This study reports an N-2 microextractor (NME) that can extract N-2 from water and supply it to catalysts on electrodes. By enhancing the supply of N-2 in the NRR process, the NME achieves efficient electrocatalytic N-2 reduction, which is of great significance to the sustainable development of the Ammonia Economy.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Engineering, Chemical

Enhancing electrocatalytic N2 reduction via tailoring the electric double layers

Haolan Tao et al.

Summary: The research on electrocatalytic nitrogen reduction reaction (NRR) is still facing challenges and urgently requires the design of highly selective catalysts. This study analyzed the impact of EDL, mass transport, and NRR kinetics on the reaction through a theoretical framework, providing insights into the relationship between N-2 diffusion and activity in different environmental conditions.

AICHE JOURNAL (2022)

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Review Chemistry, Physical

Interfacial Electrolyte Effects on Electrocatalytic CO2 Reduction

Bangwei Deng et al.

Summary: This review focuses on discussing the role and effects of electrolytes on CO2RR, including their compositions and local chemical environment. In-depth investigations on the detection of intermediates during the catalytic reactions are also included. The fundamental understanding of interfacial electrolyte effects is emphasized for maximizing and balancing the catalytic performance of CO2RR.

ACS CATALYSIS (2022)

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Article Electrochemistry

Interfacial pH Measurements Using a Rotating Ring-Disc Electrode with a Voltammetric pH Sensor

Mariana C. O. Monteiro et al.

Summary: Electrochemical reactions that involve production or consumption of H+ or OH- ions can impact the pH near the electrode surface. This study focused on probing the interfacial pH under mass transport control using a rotating ring-disc electrode coupled with a voltammetric pH sensor. By functionalizing the gold ring to detect interfacial disc pH, the method demonstrated superior sensitivity and time resolution compared to potentiometric sensors. Investigations into the effects of current density, potential, buffer capacity, and rotation rate on local pH were conducted, showing a reliable and sensitive method for accurately probing the reaction environment.

CHEMELECTROCHEM (2022)

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Article Chemistry, Multidisciplinary

High-Efficiency N2 Electroreduction Enabled by Se-Vacancy-Rich WSe2-x in Water-in-Salt Electrolytes

Peng Shen et al.

Summary: Combining catalyst and electrolyte engineering, a high-efficiency electrocatalytic nitrogen reduction reaction (NRR) is achieved using a Se-vacancy-rich WSe2-x catalyst in water-in-salt electrolyte (WISE), which suppresses H2 evolution, improves N2 affinity, and enhances active site pi-back-donation ability for promoting both activity and selectivity of NRR. The WSe2-x in 12m LiClO4 exhibits excellent faradaic efficiency and NH3 yield, among the highest reported to date.

ACS NANO (2022)

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Article Chemistry, Multidisciplinary

Aprotic Solvent Exposes an Altered Mechanism for Copper-Catalyzed Ethylene Electrosynthesis

An T. Chu et al.

Summary: In this study, the authors investigated the electroreduction of CO in an aprotic solvent-based electrolyte, revealing potential new mechanistic pathways. The results showed the formation of various C-2 products, such as ethylene, acetate, ethylene glycol, and ethane, on a polycrystalline Cu catalyst. The findings suggest a different mechanism involving proton-coupled electron transfer steps and highlight the significance of the solvent environment and proton donor in CO electroreduction.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Multidisciplinary

Electrocatalytic Reduction of Nitrogen to Ammonia in Ionic Liquids

Yuan Tian et al.

Summary: In this perspective, the fundamentals and role of ionic liquids in the electrocatalytic nitrogen reduction reaction (NRR) process are summarized, along with the selection principles, application issues, and future development directions for the electrocatalytic NRR process.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Physical

Pathways for the Formation of C2+Productsunder Alkaline Conditions during the Electrochemical Reduction of CO2

Joseph A. Gauthier et al.

Summary: This study investigates the mechanism of CO2RR under experimental conditions and reveals the differences in activation barriers between alkaline and acidic pathways, as well as the kinetic favorability of COH formation under high overpotential.

ACS ENERGY LETTERS (2022)

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Review Chemistry, Multidisciplinary

A practical guide to electrosynthesis

Matthew C. Leech et al.

Summary: Organic electrosynthesis is an important discipline that utilizes electricity for redox reactions. This Review covers the fundamental aspects of the field, practical tips, and the basics of electroanalytical techniques.

NATURE REVIEWS CHEMISTRY (2022)

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Letter Chemistry, Physical

Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction

Jaecheol Choi et al.

NATURE CATALYSIS (2022)

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Article Chemistry, Physical

Electrochemical CO2 Reduction on Polycrystalline Copper by Modulating Proton Transfer with Fluoropolymer Composites

Hanqing Pan et al.

Summary: Electrochemical reduction of CO2 to alcohols and hydrocarbon fuels offers a sustainable pathway for mitigating atmospheric CO2 while generating value-added products. The selectivity of Cu-based CO2 reduction electrocatalysts can be tuned by controlling proton-transfer dynamics, resulting in higher yields of desirable carbon-containing products.

ACS APPLIED ENERGY MATERIALS (2022)

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Review Chemistry, Multidisciplinary

Electrolyte Effects on CO2 Electrochemical Reduction to CO

Giulia Marcandalli et al.

Summary: The electrochemical reduction of CO2 faces challenges such as low energy and Faradaic efficiencies due to concurrent electrochemical reactions and solution acid-base reactions. Recent studies have shown that the nature of the electrolyte, specifically pH and cation identity, plays a crucial role in tuning the efficiency of CO2RR to CO in aqueous solutions.

ACCOUNTS OF CHEMICAL RESEARCH (2022)

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Review Engineering, Chemical

Electrocatalytic green ammonia production beyond ambient aqueous nitrogen reduction

Dazhi Yao et al.

Summary: Ammonia is the second highest produced chemical in the world and is used for fertilizer production and as a carrier for renewable energy. The current production process for ammonia has high energy consumption, emissions, and capital investment, leading to the need for efficient alternatives. Electrocatalysis technologies, particularly the nitrogen reduction reaction, have great potential but face intrinsic limitations. This review discusses the roadmap towards green ammonia and explores emerging strategies beyond conventional catalyst design and engineering.

CHEMICAL ENGINEERING SCIENCE (2022)

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Article Chemistry, Multidisciplinary

Electrocatalytic CO2-to-C2+ with Ampere-Level Current on Heteroatom-Engineered Copper via Tuning *CO Intermediate

Min Zheng et al.

Summary: Ampere-level CO2-to-C2+ electrolysis is achieved by heteroatom engineering on Cu catalysts, which demonstrates high CO2-to-C2+ productivity and Faradaic efficiency under a large current density.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

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Article Chemistry, Physical

Selective CO2 Electromethanation on Surface-Modified Cu Catalyst by Local Microenvironment Modulation

Yaoxuan Shi et al.

Summary: By modulating the ligands on the copper surface, high rates of methane electrogeneration can be achieved. The use of glutathione-modified copper electrode has resulted in efficient conversion of CO2 to CH4, offering a new approach for designing highly selective CO2 electroreduction catalysts.

ACS CATALYSIS (2022)

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Review Chemistry, Multidisciplinary

Turning Waste into Wealth: Sustainable Production of High-Value-Added Chemicals from Catalytic Coupling of Carbon Dioxide and Nitrogenous Small Molecules

Sisi Liu et al.

Summary: Efficient carbon dioxide capture and utilization (CCU) techniques are expected to provide economic benefits and stimulate the production of valuable chemicals for carbon neutrality. This review highlights the research progress in sustainable production of high-value-added chemicals through catalytic coupling of CO2 and nitrogenous small molecules.

ACS NANO (2022)

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Review Chemistry, Multidisciplinary

Advancing the Electrochemistry of Gas-Involved Reactions through Theoretical Calculations and Simulations from Microscopic to Macroscopic

Yanzheng He et al.

Summary: This paper reviews the progress and application of density functional theory (DFT), molecular dynamics (MD) simulations, and finite element simulation (FES) in gas-involved electrochemical reactions. It emphasizes the significance of theoretical calculations and simulations in understanding reaction mechanisms, establishing composition-structure-activity relationships, and predicting prospective electrocatalysts and systems. The paper also highlights notable work in utilizing DFT, MD, and FES to investigate catalyst properties and restore reaction systems from different temporal and spatial scales.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Multidisciplinary Sciences

Unconventional interfacial water structure of highly concentrated aqueous electrolytes at negative electrode polarizations

Chao-Yu Li et al.

Summary: The authors investigate the double-layer structure at the interface between a water-in-salt electrolyte and an Au(111) electrode using in situ Raman spectroscopy and molecular dynamics simulations. They observe that the physicochemical behaviors of the double-layer structure in water-in-salt electrolytes are quantitatively different from those in electrolyte solutions with lower concentrations. This understanding provides insights for designing future aqueous electrolytes for electrochemical energy storage devices.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Physical

Boosting electrochemical nitrogen reduction performance through water-in-salt electrolyte

Mengdi Liu et al.

Summary: This study reports the use of oxygen vacancy rich TiO2 loaded with Au nanoparticles as a catalyst for NRR, achieving a high Faradaic efficiency and NH3 yield rate in a super concentrated water-in-salt electrolyte solution. The study also demonstrates the hindrance of the competing hydrogen evolution reaction and suggests a new approach to improve NRR selectivity.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Environmental

Distorted spinel ferrite heterostructure triggered by alkaline earth metal substitution facilitates nitrogen localization and electrocatalytic reduction to ammonia

Yuzhuo Jiang et al.

Summary: In this study, a distorted spinel ferrite heterostructure was designed to achieve efficient electrocatalytic nitrogen reduction reaction (NRR). By optimizing the structural/electronic configurations, the activity and selectivity of NRR were greatly enhanced, leading to outstanding NRR performance.

CHEMICAL ENGINEERING JOURNAL (2022)

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Review Chemistry, Multidisciplinary

Fe-based catalysts for nitrogen reduction toward ammonia electrosynthesis under ambient conditions

Haiding Zhu et al.

Summary: This article summarizes recent advances and research progress in non-noble Fe-based catalysts used for NH3 electrosynthesis. Various synthetic protocols, structure/morphology modification, performance improvement, and reaction mechanisms are comprehensively presented. Based on recent experimental and theoretical studies, we aim to illuminate the structure-property relationship and offer an excellent opportunity for engineering advanced Fe-based catalysts for nitrogen fixation.

SUSMAT (2022)

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Review Chemistry, Multidisciplinary

Turning Waste into Wealth: Sustainable Production of High-Value-Added Chemicals from Catalytic Coupling of Carbon Dioxide and Nitrogenous Small Molecules

Sisi Liu et al.

Summary: Carbon neutrality is a central topic that concerns both the scientific community and human society. This review highlights the research progress in the sustainable production of high-value-added chemicals through the catalytic coupling of CO2 and nitrogenous small molecules. The formation of C-N bonds is a key mechanistic step in nitrogen-integrated CO2 reduction, and the review discusses possible pathways and catalytic attributes for C-N coupling. The review also proposes research directions and prospects for comprehensive improvement of C-N coupling systems.

ACS NANO (2022)

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Review Chemistry, Multidisciplinary

Customizing the microenvironment of CO2 electrocatalysis via three-phase interface engineering

Xianlong Zhou et al.

Summary: This article critically examines the methods of surface and interface engineering in electrochemical CO2 reduction reaction (CRR) and proposes strategies to optimize the microenvironment for CRR. The focus is on diverse atomic-precision modifications to increase CO2 concentration, lower energy barriers, stabilize intermediates, and control catalytic activity and selectivity.

SMARTMAT (2022)

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Review Chemistry, Multidisciplinary

Recent progress of Bi-based electrocatalysts for electrocatalytic CO2 reduction

Dong Xia et al.

Summary: In order to tackle the issue of carbon dioxide, the applications of unary Bi electrocatalysts and binary BiSn electrocatalysts in CO2RR were studied. These catalysts demonstrate high faradaic efficiencies in producing formic acid, which has significant value in the chemical and pharmaceutical industries. Additionally, the use of solid-state electrolytes shows promise in achieving high-purity formic acid production.

NANOSCALE (2022)

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Article Chemistry, Physical

Regulating the work function of silver catalysts via surface engineering for enhanced CO2 electroreduction

Xifeng Luo et al.

Summary: This study elucidated the effect of Ag's work function on the electrochemical reduction of CO2 to CO by controlling the ratio of exposed crystalline planes. It was found that a higher proportion of Ag(110) to Ag(100) leads to a lower work function, resulting in enhanced electrochemical activity and selectivity for CO production. This research demonstrates a promising strategy to improve the electrochemical performance of metal catalysts by tuning their work functions through regulating exposed crystalline planes.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

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Article Multidisciplinary Sciences

Altering the rate-determining step over cobalt single clusters leading to highly efficient ammonia synthesis

Sisi Liu et al.

Summary: This study successfully altered the rate-determining step of ammonia synthesis by introducing cobalt single clusters into the catalyst, overcoming the energy barrier of N-2 dissociation, and achieving high ammonia yield rate and superior Faradaic efficiency.

NATIONAL SCIENCE REVIEW (2021)

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Article Energy & Fuels

Specifically Adsorbed Anions Enhance CO2 Electrochemical Reduction to CO over a Gallium Catalyst in Organic Electrolytes

Tianyou Chen et al.

Summary: This study found that the presence of Cl- in organic electrolytes can enhance the reaction rate of CO2 reduction, leading to a higher CO production rate. XPS results showed that solvated Cl- can form Ga-Cl bonds on the Ga surface, promoting electron transfer processes. The generated CO2 is ultimately converted to CO through a series of electron transfer reactions involving Cl-.

ENERGY & FUELS (2021)

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Article Chemistry, Multidisciplinary

Suppression of Hydrogen Evolution in Acidic Electrolytes by Electrochemical CO2 Reduction

Christoph J. Bondue et al.

Summary: The study focuses on the electrochemical reduction of CO2 at gold electrodes under mildly acidic conditions. Increasing the CO2 partial pressure enhances the rate of CO2 reduction and suppresses hydrogen evolution, leading to high Faradaic efficiencies close to 100%. By suppressing hydrogen evolution and using protons for water formation, the study derived a general design principle for acid CO2 electrolyzers to match the mass transfer of protons to the electrode surface.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

The Role of Organic Promoters in the Electroreduction of Carbon Dioxide

Dmitry V. Vasilyev et al.

Summary: This review classifies and describes the roles of various organic promoters in the electrochemical reduction of carbon dioxide (CO2RR), highlighting key considerations to prevent errors and pave the way for industrial implementation.

ACS CATALYSIS (2021)

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Article Materials Science, Multidisciplinary

Electrochemical synthesis of ammonia: Progress and challenges

Tingting Wu et al.

Summary: The electrochemical synthesis of ammonia, with advantages such as mild operating conditions and zero emission of carbon dioxide, is considered a promising alternative to the traditional Haber-Bosch process. Research in this field focuses on catalyst development, innovations in electrolytic cell configurations, and verification of ammonia synthesis results.

MATERIALS TODAY PHYSICS (2021)

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Review Chemistry, Multidisciplinary

Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals

Cheng Tang et al.

Summary: The emerging electrocatalytic refinery (e-refinery) is a more sustainable and environmentally friendly strategy for converting renewable feedstocks and energy sources into transportable fuels and chemicals. Challenges remain in understanding mechanistic aspects and materials design for complex reactions in e-refinery processes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Advances and Challenges for the Electrochemical Reduction of CO2 to CO: From Fundamentals to Industrialization

Song Jin et al.

Summary: The electrochemical carbon dioxide reduction reaction is an important pathway for converting renewable electricity into fuels and feedstocks, with the conversion of CO2 into CO being a promising reaction. Advancements in catalyst and electrolyte design, along with understanding the catalytic mechanism, are crucial for promoting the technology towards industrial implementation. However, there are still challenges and future directions for the industrial application of this technology.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Methanol-Mediated Electrosynthesis of Ammonia

Yongwen Ren et al.

Summary: This study demonstrates an innovative alcohol-water electrolyte system to modulate local proton concentration and the microenvironment at the electrode-electrolyte interface, boosting the selectivity of NRR. The methanol-enabled electrolyte shows record high NRR FE and ammonia yield rate, with significant enhancements compared to conventional aqueous electrolytes.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Multidisciplinary

Efficient Electrochemical Reduction of CO2 to CO in Ionic Liquids

Yanjie Hu et al.

Summary: The study found that the new IL N-octyltrimethyl ammonium 1,2,4-triazole shows outstanding performance for electrochemical reduction of CO2 to CO on the commercial Ag electrode, with a current density of up to 50.8 mAcm(-2) and a Faradaic efficiency of 90.6%. Density functional theory and Fourier Transform Infrared spectroscopy further proved the interaction mechanism between [N-1118][TRIZ] and CO2.

CHEMISTRYSELECT (2021)

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Review Chemistry, Multidisciplinary

Main-group elements boost electrochemical nitrogen fixation

Laiquan Li et al.

Summary: In this review, we critically evaluate the application of main-group elements in electrocatalytic nitrogen reduction, present methodologies for N2 activation and HER suppression, and demonstrate the potential of MGEs-based mechanisms for smart design. The conclusion shows that MGEs can significantly enhance electrochemical N2 fixation.

CHEM (2021)

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Article Chemistry, Physical

Proton-filtering covalent organic frameworks with superior nitrogen penetration flux promote ambient ammonia synthesis

Sisi Liu et al.

Summary: By controlling the diffusion of reactants and using proton-filtering covalent organic frameworks, a highly selective and active nitrogen reduction was achieved in electrochemical ammonia synthesis. This strategy optimizes mass transfer and provides guidelines for practical green ammonia production.

NATURE CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

The Controllable Reconstruction of Bi-MOFs for Electrochemical CO2 Reduction through Electrolyte and Potential Mediation

Dazhi Yao et al.

Summary: This study investigates the reconstruction of a Bi-based metal-organic framework for electrochemical CO2 reduction, demonstrating that controlling the intricate reconstruction process results in excellent activity and stability of the Bi catalyst, shedding light on the design of highly efficient electrocatalysts.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Analytical

Electrochemical conversion of CO2 to CO in organic electrolyte with Cl2 and NaHCO3 produced as byproducts

Yajian Duan et al.

Summary: A novel membrane electrolysis cell has been developed for converting CO2 into CO and producing Cl2 from NaCl oxidation. The generated CO and Cl2 can be utilized for producing high-value chemicals, thus enabling the resource utilization of CO2.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Multidisciplinary Sciences

CO2 electrolysis to multicarbon products in strong acid

Jianan Erick Huang et al.

Summary: Carbon dioxide electroreduction (CO2R) is being actively studied as a promising route to convert carbon emissions to valuable chemicals and fuels. A study found that concentrating potassium cations in the vicinity of electrochemically active sites accelerates CO2 activation to enable efficient CO2R in acid. The research achieved a high CO2R efficiency on copper at pH <1 with a single-pass CO2 utilization of 77%.

SCIENCE (2021)

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Article Multidisciplinary Sciences

Salting-out effect promoting highly efficient ambient ammonia synthesis

Mengfan Wang et al.

Summary: The electroreduction of nitrogen to ammonia offers a promising alternative to the energy-intensive Haber-Bosch process but suffers from low activity and selectivity. Here, authors demonstrate that triggering a salting-out effect in a highly concentrated electrolyte can achieve highly efficient ammonia synthesis.

NATURE COMMUNICATIONS (2021)

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Article Electrochemistry

Advancing the Anode Compartment for Energy Efficient CO2 Reduction at Neutral pH

Adele Peugeot et al.

Summary: Efficient CO2 reduction at neutral pH requires the development of electrochemical devices with minimal energy input. An original method focusing on the anode compartment was proposed, testing different catalysts, anolytes, and membranes to select components for the most energy efficient and stable CO2 reduction device. Asymmetric configurations with alkaline anolytes showed a gain in energy efficiency for carbon products, highlighting the advantages of a pH gradient.

CHEMELECTROCHEM (2021)

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Review Chemistry, Multidisciplinary

Role of oxygen-bound reaction intermediates in selective electrochemical CO2 reduction

Xing Zhi et al.

Summary: This review focuses on the important role of oxygen-bound intermediates in affecting the selectivity of CO2 reduction products, and outlines practical techniques and strategies for probing the evolution of intermediates and promoting the selectivity of electrocatalysts. The study highlights the preferred reaction pathways to certain products when regulated by oxygen-bound species, based on theoretical calculations, electrochemical measurements, and operando spectroscopy observations. The geometries of these oxygen-bound intermediates and their binding on a catalyst surface determine the breakage or preservation of C-O bonds, significantly influencing the direction of selectivity towards a final product.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Regulating the oxidation state of nanomaterials for electrocatalytic CO2 reduction

Zhi-Zheng Wu et al.

Summary: Electrochemical carbon dioxide reduction reaction (CO2RR) converts CO2 into value-added chemicals and fuels, addressing renewable energy shortage and environmental pollution. Regulating the oxidation state of catalysts has been identified as an effective method for designing high-performing CO2RR catalysts that can influence catalyst activity and selectivity.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

Synergistic Promotion of the Electrochemical Reduction of Nitrogen to Ammonia by Phosphorus and Potassium

Qikun Zhang et al.

CHEMCATCHEM (2020)

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Article Chemistry, Analytical

Mapping the Potential of Zero Charge and Electrocatalytic Activity of Metal-Electrolyte Interface via a Grain-by-Grain Approach

Yufei Wang et al.

ANALYTICAL CHEMISTRY (2020)

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Review Chemistry, Physical

Understanding the Electrocatalytic Interface for Ambient Ammonia Synthesis

Lin Hu et al.

ACS ENERGY LETTERS (2020)

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Graphdiyne Interface Engineering: Highly Active and Selective Ammonia Synthesis

Yan Fang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Cu2O Nanoparticles with Both {100} and {111} Facets for Enhancing the Selectivity and Activity of CO2 Electroreduction to Ethylene

Yugang Gao et al.

ADVANCED SCIENCE (2020)

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NH2-MIL-88B-Fe for electrocatalytic N2 fixation to NH3 with high Faradaic efficiency under ambient conditions in neutral electrolyte

Xuerui Yi et al.

JOURNAL OF MATERIALS SCIENCE (2020)

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Unveiling the Essential Nature of Lewis Basicity in Thermodynamically and Dynamically Promoted Nitrogen Fixation

Mengfan Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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A Roadmap to the Ammonia Economy

Douglas R. MacFarlane et al.

JOULE (2020)

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Atypical Oxygen-Bearing Copper Boosts Ethylene Selectivity toward Electrocatalytic CO2 Reduction

Wei Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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In Situ Observation of the pH Gradient near the Gas Diffusion Electrode of CO2 Reduction in Alkaline Electrolyte

Xu Lu et al.

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Controlled Synthesis of EDTA-Modified Porous Hollow Copper Microspheres for High-Efficiency Conversion of CO2 to Multicarbon Products

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A Mn-N3 single-atom catalyst embedded in graphitic carbon nitride for efficient CO2 electroreduction

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Competing Effects of pH, Cation Identity, H2O Saturation, and N2 Concentration on the Activity and Selectivity of Electrochemical Reduction of N2 to NH3 on Electrodeposited Cu at Ambient Conditions

Nishithan C. Kani et al.

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Unique hollow Ni-Fe@MoS2 nanocubes with boosted electrocatalytic activity for N2 reduction to NH3

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Atomically Dispersed Single Ni Site Catalysts for Nitrogen Reduction toward Electrochemical Ammonia Synthesis Using N2 and H2O

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Structure Sensitivity in the Electrocatalytic Reduction of CO2 with Gold Catalysts

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Influence of Atomic Surface Structure on the Activity of Ag for the Electrochemical Reduction of CO2 to CO

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ACS CATALYSIS (2019)

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Enhanced electrocatalytic CO formation from CO2 on nanostructured silver foam electrodes in ionic liquid/water mixtures

Alexander V. Rudnev et al.

ELECTROCHIMICA ACTA (2019)

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Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts

Yao Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

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