☆ 4.8 Article

Green Synthesis for Battery Materials: A Case Study of Making Lithium Sulfide via Metathetic Precipitation

ACS APPLIED MATERIALS & INTERFACES (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Physical

Argyrodite Superionic Conductors Fabricated from Metathesis-Derived Li2S

William H. Smith et al.

Summary: This study introduces a method for the production of lithium sulfide through room-temperature metathesis. The synthesized lithium sulfide material exhibits high ionic conductivity and can be used as a critical component in next-generation batteries.

ACS APPLIED ENERGY MATERIALS (2022)

添加到收藏夹

Article Chemistry, Physical

Suitable Cathode NMP Replacement for Efficient Sustainable Printed Li-Ion Batteries

Rafal Sliz et al.

Summary: N-methyl-2-pyffolidone (NMP) is commonly used as a solvent for manufacturing cathode electrodes in the battery industry, but its negative environmental impact has led to restrictions in several countries. Dimethylformamide (DMF) is a potential replacement for NMP due to its lower boiling point and higher ignition temperature. Experimental results show that DMF can successfully replace NMP in the cathode fabrication process without compromising battery performance, reducing energy consumption and improving safety.

ACS APPLIED ENERGY MATERIALS (2022)

添加到收藏夹

Article Nanoscience & Nanotechnology

A Low-Cost Liquid-Phase Method of Synthesizing High-Performance Li6PS5Cl Solid-Electrolyte

Aiguo Han et al.

Summary: A new de novo liquid phase method has been developed to synthesize high-performance Li6PS5Cl at a lower cost, overcoming the previous drawbacks of high material cost and low performance.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹

Article Nanoscience & Nanotechnology

Lithium Sulfide: Magnesothermal Synthesis and Battery Applications

Xin Zhang et al.

Summary: This study presents a novel method for synthesizing Li2S by thermally reducing lithium sulfate with non-carbon-based reductant Mg. Compared with the traditional carbothermal method, this magnesothermal technique offers multiple advantages such as shorter reaction time, lower operation temperature, zero greenhouse gas emissions, and the formation of a valuable byproduct MgO. Furthermore, the prepared Li2S product exhibits excellent performance in lithium-sulfur batteries.

ACS APPLIED MATERIALS & INTERFACES (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Green synthesis of the battery material lithium sulfide via metathetic reactions

Liran Fang et al.

Summary: This study presents a synthesis method for lithium sulfide through spontaneous metathesis reactions between lithium salts and sodium sulfide. The method is cost-effective, scalable, and environmentally friendly, paving the way for practical solid-state lithium batteries based on SSEs.

CHEMICAL COMMUNICATIONS (2022)

添加到收藏夹

Review Chemistry, Physical

Emerging Characterization Techniques for Electrode Interfaces in Sulfide-Based All-Solid-State Lithium Batteries

Feipeng Zhao et al.

Summary: All-solid-state Li batteries (ASSLBs) based on sulfide solid-state electrolytes (SEs) have competitive ionic conductivity and decent mechanical properties, but interface issues between electrode materials and SEs hinder their high-performance development. Advanced characterization techniques provide insights into these interface issues and help propose effective strategies.

SMALL STRUCTURES (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Lithium/Sulfide All-Solid-State Batteries using Sulfide Electrolytes

Jinghua Wu et al.

Summary: All-solid-state lithium batteries (ASSLBs) are considered the next generation electrochemical energy storage devices due to their high safety and energy density, along with simple packaging and wide operable temperature range. The sulfide electrolytes, with the highest ionic conductivity among solid-state electrolytes, face challenges such as narrow electrochemical stability window, unstable electrode/electrolyte interfaces, and lithium dendrite formation. Research on emerging sulfide electrolytes and preparation methods is ongoing, focusing on achieving required properties for stable electrochemical performance and compatible interfaces in ASSLBs.

ADVANCED MATERIALS (2021)

添加到收藏夹

Review Chemistry, Physical

Recent Advances in Heterostructure Engineering for Lithium-Sulfur Batteries

Shaozhuan Huang et al.

Summary: Lithium-sulfur batteries show promise as a next-generation energy storage solution due to their economic attractiveness and high energy density, but face challenges such as the shuttling effect of lithium polysulfides and uncontrollable Li dendritic formation. Various strategies have been proposed to address these issues, with a focus on trapping polysulfides, catalyzing their conversion, and regulating Li plating/stripping. Designing and constructing heterostructured materials is seen as a promising approach to potentially resolve these challenges.

ADVANCED ENERGY MATERIALS (2021)

添加到收藏夹

Article Chemistry, Applied

Lithium sulfide nanocrystals as cathode materials for advanced batteries

Fengming Wana et al.

Summary: The article summarizes the research progress on cathodes based on lithium sulfide nanocrystals, focusing on materials synthesis and electrode fabrication methods, as well as six criteria for practical applications. It provides balanced descriptions of key chemistry, operation procedures, materials characterizations, and performance assessments, offering perspective viewpoints on future research directions.

JOURNAL OF ENERGY CHEMISTRY (2021)

添加到收藏夹

Article Multidisciplinary Sciences

A dynamic stability design strategy for lithium metal solid state batteries

Luhan Ye et al.

Summary: A multi-layered electrolyte design can inhibit the growth of lithium dendrites in solid-state lithium metal batteries, improving their performance. However, practical challenges remain in realizing a lithium metal anode for batteries.

NATURE (2021)

添加到收藏夹

Article Chemistry, Physical

Deciphering Interfacial Chemical and Electrochemical Reactions of Sulfide-Based All-Solid-State Batteries

Changhong Wang et al.

Summary: The interfacial resistance in sulfide electrolyte-based all-solid-state lithium batteries is a major challenge, caused by oxygen loss from oxide cathodes oxidizing the electrolyte and inducing structural changes. High operating voltages also create non-oxygen species. Coating strategies are effective in mitigating some issues but not all.

ADVANCED ENERGY MATERIALS (2021)

添加到收藏夹

Article Multidisciplinary Sciences

Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes

Darren H. S. Tan et al.

Summary: The research successfully achieved stable operation of silicon anodes by using the interface passivating properties of sulfide solid electrolytes. Analysis showed that this approach eliminates continuous interfacial growth and irreversible lithium losses. The promising performance of microsilicon full cells can be attributed to the ideal interface properties between microsilicon and sulfide electrolytes and the unique chemomechanical behavior of the lithium-silicon alloy.

SCIENCE (2021)

添加到收藏夹

Review Chemistry, Physical

Methods and Cost Estimation for the Synthesis of Nanosized Lithium Sulfide

Kai Yuan et al.

Summary: The study summarizes the preparation methods for Li2S nanoparticles, including laboratory synthesis methods and potential large-scale preparation routes; traditional industrial synthesis methods for commercially available Li2S are also provided as references. The scalability of these methods is mentioned, and the costs of the resulted Li2S products are estimated and compared with the currently used cathode materials for Li-ion batteries.

SMALL STRUCTURES (2021)

添加到收藏夹

Article Chemistry, Physical

Thin and Flexible Solid Electrolyte Membranes with Ultrahigh Thermal Stability Derived from Solution-Processable Li Argyrodites for All-Solid-State Li-Ion Batteries

Dong Hyeon Kim et al.

ACS ENERGY LETTERS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Electrode Design for Lithium-Sulfur Batteries: Problems and Solutions

Lei Huang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Densified Li6PS5Cl Nanorods with High Ionic Conductivity and Improved Critical Current Density for All-Solid-State Lithium Batteries

Gaozhan Liu et al.

NANO LETTERS (2020)

添加到收藏夹

Article Electrochemistry

Scalable Synthesis of Li2S Nanocrystals for Solid-State Electrolyte Applications

Yangzhi Zhao et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Liquid-phase syntheses of sulfide electrolytes for all-solid-state lithium battery

Akira Miura et al.

NATURE REVIEWS CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Physical

Metal Sulfide-Decorated Carbon Sponge as a Highly Efficient Electrocatalyst and Absorbant for Polysulfide in High-Loading Li2S Batteries

Jiarui He et al.

ADVANCED ENERGY MATERIALS (2019)

添加到收藏夹

Article Nanoscience & Nanotechnology

Properties of the Interphase Formed between Argyrodite-Type Li6PS5Cl and Polymer-Based PEO10:LiTFSI

Fabian J. Simon et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

添加到收藏夹

Article Chemistry, Applied

Facile synthesis of Li2S@C composites as cathode for Li-S batteries

Xin Chen et al.

JOURNAL OF ENERGY CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li6PS5X (X = Cl, Br, I)

Marvin A. Kraft et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Physical

A mechanochemical synthesis of submicron-sized Li2S and a mesoporous Li2S/C hybrid for high performance lithium/sulfur battery cathodes

Xiang Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

A Demonstration of Le Chatelier's Principle on the Nanoscale

Wayne Lin et al.

ACS CENTRAL SCIENCE (2017)

添加到收藏夹

Editorial Material Energy & Fuels

Firing for compactness

Yanguang Li et al.

NATURE ENERGY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reactive Precipitation of Anhydrous Alkali Sulfide Nanocrystals with Concomitant Abatement of Hydrogen Sulfide and Cogeneration of Hydrogen

Xuemin Li et al.

CHEMSUSCHEM (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synergistically Assembled Li2S/FWNTs@Reduced Graphene Oxide Nanobundle Forest for Free-Standing High-Performance Li2S Cathodes

Yan Chen et al.

ADVANCED FUNCTIONAL MATERIALS (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Nanostructured Metal Oxides and Sulfides for Lithium-Sulfur Batteries

Xue Liu et al.

ADVANCED MATERIALS (2017)

添加到收藏夹

Article Electrochemistry

Elucidating the Electrochemical Activity of Electrolyte-Insoluble Polysulfide Species in Lithium-Sulfur Batteries

Michael J. Klein et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Physical

Polysulfide-containing Glyme-based Electrolytes for Lithium Sulfur Battery

Marco Agostini et al.

CHEMISTRY OF MATERIALS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Slurryless Li2S/Reduced Graphene Oxide Cathode Paper for High-Performance Lithium Sulfur Battery

Chao Wang et al.

NANO LETTERS (2015)

添加到收藏夹

Article Chemistry, Physical

Recent Advances in Lithium Sulfide Cathode Materials and Their Use in Lithium Sulfur Batteries

Yoonkook Son et al.

ADVANCED ENERGY MATERIALS (2015)

添加到收藏夹

Article Chemistry, Physical

Application of graphite-solid electrolyte composite anode in all-solid-state lithium secondary battery with Li2S positive electrode

Tomonari Takeuchi et al.

SOLID STATE IONICS (2014)

添加到收藏夹

Article Energy & Fuels

Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio

Sheng S. Zhang

ENERGIES (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries

Yuan Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy

Yuan Yang et al.

NANO LETTERS (2010)

添加到收藏夹

Article Electrochemistry

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries

Doron Aurbach et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2009)

添加到收藏夹

Article Thermodynamics

Density and viscosity measurements of dimethoxymethane and 1,2-dimethoxyethane from 243 K to 373 K up to 20 MPa

Pingjun Zheng et al.

INTERNATIONAL JOURNAL OF THERMOPHYSICS (2008)

添加到收藏夹

Article Engineering, Environmental

Promoting sustainability through green chemistry

MM Kirchhoff

RESOURCES CONSERVATION AND RECYCLING (2005)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.