期刊
ACS APPLIED MATERIALS & INTERFACES
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.2c20731
关键词
solid oxide electrolysis cell (SOEC); oxygen electrode; degradation mechanism; pore formation; impedance spectroscopy; chemical capacitance; La0; 6Sr0; 4CoO3-? (LSC); thin film
Electrochemical impedance spectroscopy was used to investigate the chemical capacitance of LSC thin-film electrodes under anodic polarization. The study found that the chemical capacitance decreased with increasing anodic overpotentials for both dense electrodes and electrodes with open porosity. However, after annealing in synthetic air or applying high anodic bias voltages, extremely high chemical capacitance peaks were observed. These peaks were attributed to the development of closed pores in the electrodes. Model calculations based on a real-gas equation accurately predicted the experimentally obtained capacitance increase. The analysis of chemical capacitance in solid oxide electrolysis cells can serve as a nondestructive tool to detect and quantify closed porosity.
Electrochemical impedance spectroscopy was used to investigate the chemical capacitance of La0.6Sr0.4CoO3-delta (LSC) thin-film electrodes under anodic polarization (i.e., in the electrolysis mode). For this purpose, electrodes with different microstructures were prepared via pulsed-laser deposition. Analysis of dense electrodes and electrodes with open porosity revealed decreasing chemical capacitances with increasing anodic overpotentials, as expected from defect chemical considerations. However, extremely high chemical capacitance peaks with values in the range of 104 F/cm3 at overpotentials of >140 mV were obtained after annealing for several hours in synthetic air and/or after applying high anodic bias voltages of >750 mV. From the results of several surface analysis techniques and transmission electron microscopy, it is concluded that closed pores develop upon both of these treatments: (i) During annealing, initially open pores get closed by SrSO4, which forms due to strontium segregation in measurement gases with minute traces of sulfur. (ii) The bias treatment causes mechanical failure and morphological changes including closed pores in the bulk of dense films. Under anodic polarization, high-pressure oxygen accumulates in those closed pores, and this causes the capacitance peak. Model calculations based on a real-gas equation allow us to properly predict the experimentally obtained capacitance increase. We demonstrate that analysis of the chemical capacitance of oxygen electrodes in solid oxide electrolysis cells can thus be used as a nondestructive observation tool to detect and quantify closed porosity with a lower detection limit between 10-4 and 10-3.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据