Blatter Radical-Decorated Silica as a Prospective Adsorbent for Selective NO Capture from Air

Nitrogen oxides are adverse poisonous gases present in the atmosphere and having detrimental effects on the human health and environment. In this work, we propose a new type of mesoporous materials capable of capturing nitrogen monoxide (NO) from air. The designed material combines the robust Santa Barbara Amorphous-15 silica scaffold and ultrastable Blatter-type radicals acting as NO traps. Using in situ electron paramagnetic resonance spectroscopy, we demonstrate that NO capture from air is selective and reversible at practical conditions, thus making Blatter radical-decorated silica highly promising for environmental applications.

Automated summary

This work proposes a new type of mesoporous material that can capture nitrogen monoxide (NO) from air. The material combines a robust silica scaffold and radicals acting as NO traps, making it highly promising for environmental applications.