期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 16, 期 11, 页码 11191-11200出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2016.13477
关键词
Gold Nanoparticle Sensor; Colorimetric Detection; Glutathione; Didecyldimethylammonium Chloride
类别
资金
- Korea Institute of Science and Technology [2E25290, 2E25640]
- Korean Ministry of Science, ICT and Future Planning [2N39960]
- National Research Foundation of Korea [2014M3A9E1070337] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A facile, sensitive, and selective colorimetric detection method for the disinfectant, didecyldimethylammonium chloride (DDAC) in aqueous samples was developed using glutathione (GSH)-functionalized gold nanoparticles (GSH-AuNPs). DDAC shorten the interparticle distance and immediately aggregate the GSH-AuNPs, leading to a dynamic change from a wine-red to a dark purple color. Therefore, the DDAC concentration in environmental samples is detected quantitatively using the GSH-AuNP sensor by the naked eye or by UV-vis spectrophotometry. The amide carbonyl groups of GSH in this sensor coordinate to the positive ammonium ion center of DDAC and also participate in cross-linking. Moreover, the sensitivity of detection was improved and stabilized by adjusting pH and salt concentration, yielding 9.6-times higher sensitivity and a faster color change in the optimized GSH-AuNP system. The ratios of absorptions at 662 nm and 520 nm (A(662)/A(520)) of the modified AuNP solution exhibited a linear correlation with DDAC concentrations with a 1.2-ppm detection limit. The GSH-AuNPs bound to DDAC showed excellent selectivity compared to other quaternary ammonium compounds and metal cations. This cost-effective and selective sensing system allows for the rapid and facile determination of DDAC concentrations in aqueous samples.
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