Synthesis, Characterization, and Structure of Mixed-Ligand Cobalt (II) Complex with N, O Donor Sites

A mononuclear octahedral mixed-ligand cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1) has been prepared by using H2L (N,N'-dimethyl-N,N'-bi(2-hydroxy-3,5-di methyl benzyl)-ethylenediamine) as a facially coordinating tetradentate ligand with a N2O2 donor center along with sodium benzoate as an ancillary ligand. Complex 1 has been characterized by a single-crystal X-ray diffraction study, as well as by other spectroscopic tools. The complex crystallizes in the monoclinic space group C-2 with a = 31.73(3) angstrom, b = 7.868(3) angstrom, c = 19.131(15) angstrom, and beta = 125.25(3)degrees. The single-crystal X-ray diffraction study shows that in the mononuclear cobalt (II) complex [Co(H2L)(PhCOO)(2)] (1), the metal center adopts an octahedral environment.

Automated summary

A mononuclear octahedral mixed-ligand cobalt (II) complex has been synthesized and characterized by single-crystal X-ray diffraction study. The complex adopts an octahedral environment with a facially coordinating tetradentate ligand and an ancillary ligand.