期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 217, 期 -, 页码 51-56出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molliq.2015.08.041
关键词
Organogel; Soft material; Eu complex; Gelaphilic; Solvophilic
资金
- JSPS KAKENHI [25410211]
- JST A-STEP [AS262Z00783M]
- Shimane Industrial Promotion foundation
- Nanotechnology Platform Program (Molecule and Material Synthesis) of MEXT, Japan
- Institute for Molecular Science
- Cooperative Research Project of Research Institute of Electronics, Shizuoka University
- Grants-in-Aid for Scientific Research [25410211] Funding Source: KAKEN
The rare-earth complexes [Eu(hfa)(3)(phen)] and [Eu(hfa)(3)(TPPO)(2)]were dispersed in the fibrous network structure of an organogel of phenol and surfactant AOT. Steady-state and time-resolved emission properties arising from the complex-organogel interactions of these two complexes were investigated. The results suggest that [Eu(hfa)(3)(phen)] localizes around the fibrous structure of the organogel architecture, whereas [Eu(hfa)(3)(TPPO)(2)] favors the solvent domain even when dispersed in the gel environment. These properties characterize the steady state and time -resolved behavior in the emission processes of the [Eu(hfa)(3)(phen)] and [Eu(hfa)(3)(TPPo)(2)] complexes, which can be regarded as gelaphilic and solvophilic, respectively. (C) 2015 Elsevier B.V. All rights reserved.
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