期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 416, 期 -, 页码 20-28出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2016.02.015
关键词
Hybrid; Artificial metalloenzyme; Catalysis; Oxidation; Non heme iron
资金
- Agence Nationale pour la Recherche [ANR 08-CP2D-12]
- Region Rhone Alpes for a CIBLE grant
- Labex Arcane [ANR-11-LABX-0003-01]
A new artificial oxidase has been developed for selective transformation of thioanisole. The catalytic activity of an iron inorganic complex, FeLibu, embedded in a transport protein NikA has been investigated in aqueous media. High efficiency (up to 1367 t), frequency 459 TON min(-1) and selectivity (up to 69%) make this easy to use catalytic system an asset for a sustainable chemistry. (C) 2016 Elsevier B.V. All rights reserved.
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