4.7 Review

A review of future directions in the development of sustainable carbon fiber from bio-based precursors

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Article Biochemistry & Molecular Biology

Chemically Accelerated Stabilization of a Cellulose-Lignin Precursor as a Route to High Yield Carbon Fiber Production

Nguyen-Duc Le et al.

Summary: Producing carbon fiber from bio-based or renewable resources has attracted much attention in recent years. The stabilization process, which transforms the precursor fiber to withstand high temperatures, is a critical step. This study used thermogravimetric analysis to explore different stabilization profiles and investigated the influence of atmosphere, cellulose-lignin composition, and catalysts on carbon yield and stabilization rate. It was found that a phosphorus-based flame retardant greatly enhanced the char yield, doubling the amount produced.

BIOMACROMOLECULES (2022)

Article Chemistry, Applied

Cellulose-lignin composite fibres as precursors for carbon fibres. Part 1-Manufacturing and properties of precursor fibres

Mikaela Trogen et al.

Summary: Cellulose-lignin composite fibres were successfully spun from ionic liquid solutions with lignin concentrations of up to 50%. Comparing beech and spruce lignin, the higher stability and carbon content of spruce lignin resulted in higher carbon fiber yield. These composite fibres show great potential as precursors for carbon fiber production.

CARBOHYDRATE POLYMERS (2021)

Article Materials Science, Paper & Wood

Effect of boric acid on the stabilisation of cellulose-lignin filaments as precursors for carbon fibres

Nguyen-Duc Le et al.

Summary: Treating composite fibers with boric acid can reduce stabilization time, decrease fiber fusion, and significantly increase carbon yield.

CELLULOSE (2021)

Article Materials Science, Paper & Wood

Understanding the influence of key parameters on the stabilisation of cellulose-lignin composite fibres

Nguyen-Duc Le et al.

Summary: The study explores the potential of composite fibre made from blended cellulose and lignin as a low-cost and sustainable alternative to carbon fibre. Further research is needed to develop production methods, while investigating stabilization processes and fibre properties can address related issues.

CELLULOSE (2021)

Article Chemistry, Multidisciplinary

Enhancing the multi-functional properties of renewable lignin carbon fibers via defining the structure-property relationship using different biomass feedstocks

Qiang Li et al.

Summary: Lignin has been extensively studied as a renewable precursor for carbon materials, but the mechanisms by which its structure affects the properties of carbon fibers are still not fully understood, including mechanical and electroconductive performances. Research has shown that the structural characteristics of lignin, such as the content of beta-O-4 linkages, are significantly correlated with the mechanical and electroconductive properties of carbon fibers, with higher linear beta-O-4 linkages promoting better fiber performance.

GREEN CHEMISTRY (2021)

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Characterization of the adhesive properties between structural battery electrolytes and carbon fibers

Johanna Xu et al.

COMPOSITES SCIENCE AND TECHNOLOGY (2020)

Article Engineering, Multidisciplinary

Low cost textile-grade carbon-fiber epoxy composites for automotive and wind energy applications

Nitilaksha Hiremath et al.

COMPOSITES PART B-ENGINEERING (2020)

Article Chemistry, Multidisciplinary

Fungal Treatment Modifies Kraft Lignin for Lignin- and Cellulose-Based Carbon Fiber Precursors

Joona Mikkila et al.

ACS OMEGA (2020)

Article Biochemistry & Molecular Biology

Biopolymer blends from hardwood lignin and bio-polyamides: Compatibility and miscibility

R. Muthuraj et al.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2019)

Article Chemistry, Multidisciplinary

Carbon Fibers from Lignin-Cellulose Precursors: Effect of Stabilization Conditions

Andreas Bengtsson et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Review Chemistry, Physical

A review of oxygen reduction mechanisms for metal-free carbon-based electrocatalysts

Ruguang Ma et al.

NPJ COMPUTATIONAL MATERIALS (2019)

Article Green & Sustainable Science & Technology

Wet-Spinning and Carbonization of Lignin-Polyvinyl Alcohol Precursor Fibers

Marie Follmer et al.

ADVANCED SUSTAINABLE SYSTEMS (2019)

Review Chemistry, Multidisciplinary

Are lignin-derived carbon fibers graphitic enough?

William J. Sagues et al.

GREEN CHEMISTRY (2019)

Review Chemistry, Physical

Biomass-derived porous carbon materials with different dimensions for supercapacitor electrodes: a review

Zhihong Bi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Review Materials Science, Multidisciplinary

On the morphology and structure formation of carbon fibers from polymer precursor systems

Muhannad Al Aiti et al.

PROGRESS IN MATERIALS SCIENCE (2018)

Article Chemistry, Multidisciplinary

Biobased Structurally Compatible Polymer Blends Based on Lignin and Thermoplastic Elastomer Polyurethane as Carbon Fiber Precursors

Mario Culebras et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Materials Science, Paper & Wood

Enhanced stabilization of cellulose-lignin hybrid filaments for carbon fiber production

Nolene Byrne et al.

CELLULOSE (2018)

Review Polymer Science

Recent Developments in Carbon Fibers and Carbon Nanotube-Based Fibers: A Review

Nitilaksha Hiremath et al.

POLYMER REVIEWS (2017)

Review Forestry

Lignin pyrolysis reactions

Haruo Kawamoto

JOURNAL OF WOOD SCIENCE (2017)

Article Materials Science, Multidisciplinary

Cellulose-Derived Carbon Fibers with Improved Carbon Yield and Mechanical Properties

Johanna M. Spoerl et al.

MACROMOLECULAR MATERIALS AND ENGINEERING (2017)

Article Multidisciplinary Sciences

Renewable acrylonitrile production

Eric M. Karp et al.

SCIENCE (2017)

Article Chemistry, Multidisciplinary

Preparation and Characterization of Lignosulfonate-Acrylonitrile Copolymer as a Novel Carbon Fiber Precursor

Keqiang Xia et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2016)

Review Polymer Science

Recent advances in carbon fibers derived from biobased precursors

Amod A. Ogale et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2016)

Article Chemistry, Applied

Acrylonitrile from Biomass: Still Far from Being a Sustainable Process

Robert K. Grasselli et al.

TOPICS IN CATALYSIS (2016)

Article Materials Science, Multidisciplinary

Carbon fibers prepared from ionic liquid-derived cellulose precursors

Johanna M. Spoerl et al.

MATERIALS TODAY COMMUNICATIONS (2016)

Article Chemistry, Applied

Metrics of acrylonitrile: From biomass vs. petrochemical route

M. Olga Guerrero-Perez et al.

CATALYSIS TODAY (2015)

Article Engineering, Chemical

Lumped Kinetics for Biomass Tar Cracking Using 4-Propylguaiacol as a Model Compound

Elmer B. Ledesma et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2015)

Article Chemistry, Physical

From cellulose fibrils to single chains: understanding cellulose dissolution in ionic liquids

Xueming Yuan et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Article Chemistry, Multidisciplinary

Processing, Structure, and Properties of Lignin- and CNT-Incorporated Polyacrylonitrile-Based Carbon Fibers

H. Clive Liu et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2015)

Article Materials Science, Multidisciplinary

Characterization of the major reactions during conversion of lignin to carbon fiber

Hendrik Mainka et al.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2015)

Article Materials Science, Multidisciplinary

Carbon Fibers from UV-Assisted Stabilization of Lignin-Based Precursors

Meng Zhang et al.

FIBERS (2015)

Review Chemistry, Multidisciplinary

Carbon Fibers: Precursor Systems, Processing, Structure, and Properties

Erik Frank et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Physical

Carbon fibers from dry-spinning of acetylated softwood kraft lignin

Meng Zhang et al.

CARBON (2014)

Article Materials Science, Multidisciplinary

Carbonization behavior of oxidized viscose rayon fibers in the presence of boric acid-phosphoric acid impregnation

Ismail Karacan et al.

JOURNAL OF MATERIALS SCIENCE (2014)

Article Materials Science, Paper & Wood

Improvement of Mechanical Properties of Softwood Lignin-Based Carbon Fibers

Jian Lin et al.

JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY (2014)

Article Materials Science, Multidisciplinary

Preparation and Characterization of Interconnected, Kraft Lignin-Based Carbon Fibrous Materials by Electrospinning

Ian Dallmeyer et al.

MACROMOLECULAR MATERIALS AND ENGINEERING (2014)

Article Chemistry, Physical

Enhancing the carbon yield of cellulose based carbon fibres with ionic liquid impregnates

Nolene Byrne et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

Article Chemistry, Multidisciplinary

Ultrastrong Fibers Assembled from Giant Graphene Oxide Sheets

Zhen Xu et al.

ADVANCED MATERIALS (2013)

Article Chemistry, Applied

Study on carbonization of lignin by TG-FTIR and high-temperature carbonization reactor

Jun Cao et al.

FUEL PROCESSING TECHNOLOGY (2013)

Article Biochemistry & Molecular Biology

Study on structure and thermal stability properties of lignin during thermostabilization and carbonization

Yamin Li et al.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2013)

Article Polymer Science

Orientation of Carbon Fiber Precursors from 1-Butyl-3-Metylimidazoluim Chloride Cellulose Solutions

Rhea J. Sammons et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2013)

Article Polymer Science

A new method for stabilizing softwood kraft lignin fibers for carbon fiber production

Ida Norberg et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2013)

Article Chemistry, Multidisciplinary

Patterned Functional Carbon Fibers from Polyethylene

Marcus A. Hunt et al.

ADVANCED MATERIALS (2012)

Article Polymer Science

On the characterization and spinning of an organic-purified lignin toward the manufacture of low-cost carbon fiber

Darren A. Baker et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2012)

Article Materials Science, Multidisciplinary

Novel Cellulose/Polymer Blend Fibers Obtained Using Ionic Liquids

Denis Ingildeev et al.

MACROMOLECULAR MATERIALS AND ENGINEERING (2012)

Review Materials Science, Multidisciplinary

Carbon Fibers: Precursors, Manufacturing, and Properties

Erik Frank et al.

MACROMOLECULAR MATERIALS AND ENGINEERING (2012)

Article Materials Science, Multidisciplinary

Preparation of carbon fibers from a lignin copolymer with polyacrylonitrile

Sanjeev P. Maradur et al.

SYNTHETIC METALS (2012)

Article Chemistry, Analytical

Thermal reactivities of catechols/pyrogallols and cresols/xylenols as lignin pyrolysis intermediates

Mohd Asmadi et al.

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS (2011)

Review Polymer Science

Chitosan: a New Versatile Bio-polymer for Various Applications

Debasish Sahoo et al.

DESIGNED MONOMERS AND POLYMERS (2009)

Article Chemistry, Physical

Carbon fiber from natural biopolymer Bombyx mori silk fibroin with iodine treatment

Md. Majibur Rahman Khan et al.

CARBON (2007)

Article Engineering, Environmental

Formation of cyclopentadienyl radical from the gas-phase pyrolysis of hydroquinone, catechol, and phenol

Lavrent Khachatryan et al.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2006)

Article Engineering, Environmental

Lignin-based carbon fibers: Effect of synthetic polymer blending on fiber properties

S Kubo et al.

JOURNAL OF POLYMERS AND THE ENVIRONMENT (2005)

Article Polymer Science

Lyocell fibers as the precursor of carbon fibers

SJ Peng et al.

JOURNAL OF APPLIED POLYMER SCIENCE (2003)

Article Chemistry, Applied

Oxidation and pyrolysis of chitosan as a route for carbon fiber derivation

M Bengisu et al.

CARBOHYDRATE POLYMERS (2002)

Article Chemistry, Physical

Lignin-based carbon fibers for composite fiber applications

JF Kadla et al.

CARBON (2002)

Article Materials Science, Composites

Conversion of cellulosic fibres into carbon fibres: a study of the mechanical properties and correlation with chemical structure

H Plaisantin et al.

COMPOSITES SCIENCE AND TECHNOLOGY (2001)