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Article
Chemistry, Multidisciplinary
Xi Zhang et al.
Summary: This review highlights the recent progress and applications of electrochemical nitrite reduction, including the preparation of gaseous and liquid products, catalyst selection, and understanding of reaction mechanisms. The challenges and opportunities in this field are analyzed as well.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Guilai Wen et al.
Summary: Ammonia plays a crucial role in agriculture and industry, but its traditional production methods suffer from environmental pollution and high energy consumption. This study introduces a highly efficient electrocatalyst that can convert nitrite into ammonia at room temperature, achieving high yield rates and selectivity.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Peng Shen et al.
Summary: Combining catalyst and electrolyte engineering, a high-efficiency electrocatalytic nitrogen reduction reaction (NRR) is achieved using a Se-vacancy-rich WSe2-x catalyst in water-in-salt electrolyte (WISE), which suppresses H2 evolution, improves N2 affinity, and enhances active site pi-back-donation ability for promoting both activity and selectivity of NRR. The WSe2-x in 12m LiClO4 exhibits excellent faradaic efficiency and NH3 yield, among the highest reported to date.
Article
Chemistry, Multidisciplinary
Xingchuan Li et al.
Summary: In this study, PdFe1 single-atom alloy is developed as an effective electrocatalyst for nitrogen reduction reaction (NRR). Mechanistic investigations reveal that Pd-coordinated Fe single atoms serve as active centers, enabling efficient N-2 activation and exhibiting high selectivity and stability for the NRR.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Physical
Yong Liu et al.
Summary: This study successfully developed efficient catalysts for the reduction of nitrate to ammonia by fabricating a series of CuNi alloy nanoparticles embedded in nitrogen-doped carbon matrix. The catalysts exhibited excellent selectivity and faradaic efficiency, surpassing the performance of monometallic catalysts. The reaction mechanism and key intermediates were revealed through experimental and computational methods. This work provides a new synthetic route for bimetallic catalysts and enhances the understanding of the nitrate to ammonia reaction.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
Zhifeng He et al.
Summary: Molybdenum-based catalysts have been proven effective in nitrogen reduction reactions due to their high affinity towards nitrogen. This study demonstrates the improved electrocatalytic performance of nitrogen reduction to ammonia through the design of heterostructures and the introduction of defects, such as vacancies and heteroatom doping, in Mo-based catalysts.
ACS APPLIED NANO MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Jiali Lv et al.
Summary: Electrochemical N-2 reduction reaction (NRR) is an alternative method for producing ammonia under ambient conditions. However, the slow kinetics and competition from the hydrogen evolution reaction hinder the catalytic activity and selectivity of NRR catalysts. In this study, gold-modified molybdenum carbide nanoparticles supported on nitrogen-doped carbon nanotubes were synthesized and demonstrated to enhance the NRR performance.
ACS APPLIED NANO MATERIALS
(2022)
Article
Chemistry, Inorganic & Nuclear
Zhaofei Ren et al.
Summary: Electrocatalytic reduction of nitrite to NH3 can be efficiently achieved using oxygen vacancy-rich A-TiO2-x nanoarray as a superb catalyst, which exhibits excellent catalytic performance and durability. Additionally, this nanoarray can be applied in Zn-NO2- batteries, delivering high power density and NH3 yield.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Physical
Qian Liu et al.
Summary: Cu3P nanoribbon is proposed as a highly efficient electrocatalyst for the conversion of nitrogen to ammonia. It shows excellent catalytic performance and stability under benign conditions and achieves high Faradaic efficiency and large yield.
Article
Chemistry, Physical
Bin Wang et al.
Summary: This study proposes a simple and efficient carbonization strategy to fabricate superelastic and fatigue-resistant carbon nanofiber aerogels. The use of (NH4)2SO4 during the carbonization process enables the retention of the three-dimensional interconnected honeycomb-like structure, resulting in exceptional mechanical performances and sensitivity for the CNFAs-based sensor. The CNFAs exhibit high compressibility, superelasticity, fatigue resistance, and are capable of monitoring signals of the human body, spatial pressure, and voice recognition, making them highly attractive for flexible wearable devices.
Article
Chemistry, Physical
Qian Liu et al.
Summary: In this study, an efficient electrocatalyst consisting of Ag nanoarray and NiO nanosheets array on carbon cloth as support was reported for the selective reduction of nitrite to ammonia. The catalyst exhibited high ammonia yield and Faradaic efficiency in alkaline solution.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Inorganic & Nuclear
Hai-jun Chen et al.
Summary: In this study, a novel electrocatalyst, OV-Ti2O3, was reported for sustainable NH3 production. OV-Ti2O3 exhibited outstanding N-2 fixation performance in experiments and showed excellent performance in the assembled Zn-N-2 battery.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Electrochemistry
Shaoxiong Li et al.
Summary: The study reports a three-dimensional catalyst for the reduction of NO2- to produce NH3, demonstrating high activity, excellent selectivity, and durability.
Article
Nanoscience & Nanotechnology
Sujin Seok et al.
Summary: In this study, a Ni-based core-shell material (Ni@Ni-NC) was produced through heat treatment, demonstrating excellent electrocatalytic OER performance with over- and onset potentials better than commercial IrO2. The well-dispersed Ni-NC species and core-shell structures play key roles in improving the electrocatalytic OER performance. Density functional theory (DFT) calculations indicate a dual-site OER mechanism with low reaction barrier for the Ni-NC active species.
ACS APPLIED NANO MATERIALS
(2021)
Review
Chemistry, Physical
Longcheng Zhang et al.
Summary: This review discusses recent progress in electrocatalytic water splitting using advanced electrospun nanomaterials, covering fundamentals, structure design, and electrocatalytic properties. The review highlights the importance of designing 1D nanocatalysts with large surface area, high electronic conductivity, and tunable composition to improve the efficiency of electrochemical water splitting. The future perspectives and challenges in designing next-generation 1D electrospun nanocatalysts for electrochemical water splitting are also outlined.
Article
Chemistry, Multidisciplinary
Jie Liang et al.
Summary: The study introduces a Cu3P nanowire array supported on copper foam as an efficient electrocatalyst for nitrite-to-ammonium conversion in neutral media. This catalyst demonstrates high ammonium yield rates, Faradaic efficiencies, and stability.
Article
Chemistry, Physical
Changhong Wang et al.
Summary: In this study, Ni nanosheet arrays with Ni vacancies exhibited outstanding electrocatalytic performances towards selective nitrite reduction to ammonia and semi-dehydrogenation of tetrahydroisoquinolines. The decrease in electronic cloud density induced by the Ni vacancies improved NO2- adsorption and NH3 desorption, leading to high performance in nitrite-to-ammonia conversion. Additionally, a bifunctional two-electrode electrolyzer was constructed for simultaneous production of ammonia and dihydroisoquinoline with robust stability and high selectivity.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Hao Li et al.
Article
Chemistry, Physical
Jacob P. Troutman et al.
Article
Engineering, Chemical
Chandrashekhar S. Patil et al.
SEPARATION AND PURIFICATION TECHNOLOGY
(2020)
Article
Ecology
Xianbin Zhu et al.
Article
Chemistry, Inorganic & Nuclear
Song Xu et al.
INORGANIC CHEMISTRY
(2019)
Article
Chemistry, Multidisciplinary
Yixing Guo et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2018)
Article
Chemistry, Multidisciplinary
Chun Tang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2017)
Article
Electrochemistry
Luca Mattarozzi et al.
ELECTROCHIMICA ACTA
(2013)
Review
Chemistry, Multidisciplinary
R Schlogl
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2003)