期刊
ACS APPLIED ENERGY MATERIALS
卷 5, 期 10, 页码 12851-12859出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.2c02455
关键词
MnON; HER; OER; photocatalysis; water splitting
资金
- National Research Foundation of Korea
- [NRF-2020R1I1A3054429]
Photocatalytic water splitting using nanocomposites of manganese oxynitride and reduced graphene oxide showed enhanced efficiency due to large surface area, increased light absorption, and interfacial charge transfer. The hydrogen evolution rates increased with the content of graphene oxide in the composites, indicating the important role of reduced graphene oxide. The photocatalysts also displayed stability and recyclability after multiple uses.
Photocatalytic water splitting has gained considerable attention owing to the sustainable nature of hydrogen as a clean energy source alternative to fossil fuels. In this study, nanocomposites consisting of manganese oxynitride and reduced graphene oxide were synthesized by the combined involvement of a solvothermal process and Hummer's method and examined for their photocatalytic applications for water splitting hydrogen production and degradation of norfloxacin as a model pollutant. Spectroscopic and structural analyses showed successful formation of the stable composite in which manganese oxynitride nanoparticles are decorated on graphene sheets. With increasing content of graphene oxide in the composite, it showed the enhanced photocatalytic efficiency in water splitting hydrogen evolution. This is well explained by the large surface area, more light absorption, and interfacial charge transfer in the composite photocatalyst. The hydrogen evolution rates of MnON nanoparticles and MnON/RGO composites of mass ratios 1:1, 1:2, and 1:3 were measured as 250.1, 456.2, 543.6, and 708.5 mu mol g-1 min-1, respectively, and the oxygen evolution rates were measured as 129.0, 229.4, 273.4, and 354.6 mu mol g-1 min-1, respectively, suggesting the important roles of reduced graphene oxide. The photocatalysts also demonstrated enhanced stability and recyclability after multiple uses.
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