4.8 Article

Tailoring layered transition metal compounds for high-performance aqueous zinc-ion batteries

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Enhanced and stabilized charge transport boosting by Fe-doping effect of V2O5 nanorod for rechargeable Zn-ion battery

Geun Yoo et al.

Summary: Due to rising fossil fuel prices and increasing energy demand, the rational utilization of renewable energy sources has become a global topic. This study reports the development of Fe-doped V2O5 nanorods to enhance the energy density and capacity retention of rechargeable aqueous zinc-ion batteries.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY (2021)

Article Multidisciplinary Sciences

Atomic-scale unveiling of multiphase evolution during hydrated Zn-ion insertion in vanadium oxide

Pilgyu Byeon et al.

Summary: The study focuses on the multiphase evolution during hydrated zinc-ion insertion in vanadium oxide cathodes using atomic-column-resolved scanning transmission electron microscopy. The research directly observed multiple intermediate phases and revealed structural correlation between these phases, highlighting the importance of smooth multiphase evolution in achieving high discharge capacity in oxide cathodes for aqueous rechargeable batteries.

NATURE COMMUNICATIONS (2021)

Article Chemistry, Physical

Alkali Ions Pre-Intercalated Layered MnO2 Nanosheet for Zinc-Ions Storage

Liyuan Liu et al.

Summary: By pre-intercalating alkali ions and water crystals into layered delta-MnO2, ultra-thin nanosheets of K0.27MnO2∙0.54H2O (KMO) and Na0.55Mn2O4∙1.5H2O were prepared, which act as pillars to stabilize the structures and enable rapid cation diffusion in the KMO structure, leading to high power capability and good cycling stability. The charge storage mechanism of KMO in an aqueous Zn-ion battery involves (de)intercalation of H3O+ with further dissolution-precipitation of Zn-4(OH)6(SO4)∙5H2O solid product on the KMO surface, as revealed by electrochemical quartz crystal microbalance measurements and in-operando X-ray diffraction techniques.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Defect-Rich MoO3 Nanobelt Cathode for a High-Performance Hybrid Alkali/Acid Zn-MoO3 Rechargeable Battery

Pingwei Cai et al.

Summary: The study introduces an alkali-acid Zn-MoO3 hybrid battery with H+ and OH- as charge carriers at the cathode and anode, respectively. By utilizing defect-rich MoO3 porous nanobelts, the battery enhances proton storage and improves electrochemical performance through density functional theory calculations.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Article Chemistry, Physical

Oxygen defect enriched (NH4)2V10O25.8H2O nanosheets for superior aqueous zinc-ion batteries

Jin Cao et al.

Summary: In this study, an advanced cathode material (NH4)2V10O25.8H2O (NVOD) with oxygen defects was reported for aqueous zinc-ion batteries, demonstrating excellent performance including high capacity, ultrahigh stability, and exceptional energy density, showing great potential for future applications.

NANO ENERGY (2021)

Article Chemistry, Physical

Flexible high-energy and stable rechargeable vanadium-zinc battery based on oxygen defect modulated V2O5 cathode

Xinyue Liang et al.

Summary: This study presents a promising binder-free V2O5 nanorods cathode material for aqueous/quasi-solid-state Zn ion batteries, exhibiting excellent high capacity, robust long-term life span, and impressive energy density. The innovative strategy of oxygen defect modulation and phosphorus doping leads to improved performance of metal oxide electrodes, paving the way for the development of efficient flexible energy storage devices and wearable electronics technology.

NANO ENERGY (2021)

Article Chemistry, Multidisciplinary

Understanding Zn-Ion Insertion Chemistry through Nonaqueous Electrochemical Investigation of 2H-NbSe2

Min Je Park et al.

Summary: The study investigates the electrochemical Zn-ion insertion into 2H-NbSe2 as a platform host using bulk and microflower particles formed of nanosheets, finding that the process is reversible and facile with the latter. The morphological characteristics and the relatively low Zn-ion migration barrier in the microflower particles contribute to the easy diffusion of Zn ions in 2H-NbSe2, highlighting the importance of weaker host-guest interaction and reduced particle size for achieving appreciable diffusion and reversible electrochemical behavior in a multivalent-ion host material.

ADVANCED MATERIALS INTERFACES (2021)

Article Chemistry, Physical

Cation- deficient Zn0.3(NH4)0.3V4O10•0.91H2O for rechargeable aqueous zinc battery with superior low- temperature performance

Tao He et al.

Summary: A novel cation-deficient nonstoichiometric Zn-0.3(NH4)(0.3)V4O10·0.91H2O (ZNV) cathode material for aqueous zinc batteries (AZBs) was reported in this research, exhibiting high discharge capacity and superior cycle stability. Both experiments and theoretical simulations demonstrated that the presence of cation vacancies facilitates Zn2+ diffusion during cycles.

ENERGY STORAGE MATERIALS (2021)

Article Chemistry, Physical

Layered Barium Vanadate Cathodes for Aqueous Zinc Batteries: Enhancing Cycling Stability through Inhibition of Vanadium Dissolution

Shizhou Luo et al.

Summary: This article successfully synthesized a cathode composed of Ba0.26V2O5·0.92H(2)O nanobelts, which can deliver high capacity in AZIBs and demonstrate excellent cycle stability and rate performance. The formation of BaSO4 cathode-electrolyte interphase film effectively inhibits the dissolution of V ions.

ACS APPLIED ENERGY MATERIALS (2021)

Review Chemistry, Physical

Emerging Intercalation Cathode Materials for Multivalent Metal-Ion Batteries: Status and Challenges

Susu Chen et al.

Summary: Recent advances in intercalation cathode materials for multivalent metal-ion batteries, such as vanadium and manganese oxides, chalcogenides, and carbon materials, have shown promising potential. However, challenges remain in terms of sluggish solid-state diffusion and slow desolvation processes at the cathode/electrolyte interface.

SMALL STRUCTURES (2021)

Review Chemistry, Multidisciplinary

Applying Machine Learning to Rechargeable Batteries: From the Microscale to the Macroscale

Xiang Chen et al.

Summary: This paper summarizes the application of machine learning in rechargeable batteries, including exploring new functional theory calculations and molecular dynamics simulations, as well as mining valuable information from experimental and theoretical datasets. This has led to the establishment of a structure-function correlation for predicting ionic conductivity and battery lifespan, along with advantages in strategy optimization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Physical

Strategies of structural and defect engineering for high-performance rechargeable aqueous zinc-ion batteries

Min Du et al.

Summary: Aqueous zinc-ion batteries have attracted attention due to their low cost, high safety, and abundant natural resources. However, challenges such as low electrochemical activity of cathodes and sluggish diffusion kinetics of Zn2+ have restricted their practical application. Structural and defect engineering strategies have been developed to address these challenges, including introducing interlayer ions, designing amorphous structures, and constructing nanostructured anodes.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Review Chemistry, Physical

Layered electrode materials for non-aqueous multivalent metal batteries

Ahiud Morag et al.

Summary: The global transition to clean energy production has increased the demand for efficient energy storage solutions. While lithium-ion batteries have been widely used in portable electronics and electric vehicles, their application in large-scale energy storage is limited. Multivalent metal batteries, utilizing corresponding metals as anodes, present a promising alternative for overcoming the limitations of lithium-ion batteries.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Materials Science, Multidisciplinary

Modulating surficial oxygen vacancy of the VO2 nanostructure to boost its electromagnetic absorption performance

Siyao Cheng et al.

Summary: The study showed that tuning the surface oxygen vacancy of VO2 through VO2-NaBH4 grinding treatment can affect its electromagnetic absorption properties. The oxygen vacancy content is closely related to the electrical conductivity, and the performance can be adjusted by changing the mass ratio of VO2 and NaBH4.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

Article Materials Science, Multidisciplinary

Interfacial adsorption-insertion mechanism induced by phase boundary toward better aqueous Zn-ion battery

Lutong Shan et al.

Summary: In this study, a biphasic vanadate material was reported, and a novel interfacial adsorption-insertion mechanism induced by phase boundaries was detected. First-principles calculations showed that this mechanism can enhance specific capacity, reduce diffusion energy barrier, and promote faster reaction kinetics.

INFOMAT (2021)

Article Chemistry, Multidisciplinary

Principles of interlayer-spacing regulation of layered vanadium phosphates for superior zinc-ion batteries

Linfeng Hu et al.

Summary: The study addresses the challenges of sluggish Zn2+ diffusion kinetics and poor cyclic stability in cathode materials for aqueous ZIBs by synthesizing PA-intercalated VOPO4·2H2O materials with different interlayer spacing. The optimized 16.5 angstrom spacing shows enhanced zinc-ion diffusion and cycling stability, leading to improved battery performance.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Article Chemistry, Multidisciplinary

Tuning the electronic structure of layered vanadium pentoxide by pre-intercalation of potassium ions for superior room/low-temperature aqueous zinc-ion batteries

Guang Su et al.

Summary: By doping K+ into V2O5, this study promotes the diffusion of Zn2+ and enhances the structural stability of the battery; K0.5V2O5 demonstrates excellent electrochemical performance at high rates, long-term cycling, and low temperatures, showing great potential for high-performance cathodes in aqueous ZIBs.

NANOSCALE (2021)

Article Materials Science, Multidisciplinary

Weaker Interactions in Zn2+ and Organic Ion-pre-intercalated Vanadium Oxide toward Highly Reversible Zinc-ion Batteries

Feng Zhang et al.

Summary: The cathode of rechargeable aqueous zinc-ion batteries with organic cations and Zn2+ ions pre-inserted vanadium oxide shows high discharge capacity and ultra-long cycle life, indicating significant potential for practical applications in energy storage.

ENERGY & ENVIRONMENTAL MATERIALS (2021)

Article Chemistry, Physical

Anion deficiency motivated Na2V6O16 nanobelts for superior sustainable zinc ion storage

Xiaojing Liu et al.

Summary: This article presents a facile recrystallization/reduction strategy to prepare anion-deficient Na2V6O16 nanobelt for rechargeable zinc ion batteries (ZIBs), demonstrating superior high specific capacity and long-term reliability. The oxygen vacancy in the nanobelt enhances V-O bonds and improves electrical conductivity, contributing to favorable zinc storage ability even at large current density.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

Uncovering the Potential of M1-Site-Activated NASICON Cathodes for Zn-Ion Batteries

Pu Hu et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Sustainable Recycling Technology for Li-Ion Batteries and Beyond: Challenges and Future Prospects

Ersha Fan et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Multidisciplinary

H+-Insertion Boosted α-MnO2 for an Aqueous Zn-Ion Battery

Xu Gao et al.

Article Nanoscience & Nanotechnology

Rechargeable Aqueous Zinc-Ion Batteries in MgSO4/ZnSO4 Hybrid Electrolytes

Yingmeng Zhang et al.

NANO-MICRO LETTERS (2020)

Article Chemistry, Multidisciplinary

A High Performing Zn-Ion Battery Cathode Enabled by In Situ Transformation of V2O5Atomic Layers

Yanying Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Energy & Fuels

Current status and future directions of multivalent metal-ion batteries

Yanliang Liang et al.

NATURE ENERGY (2020)

Article Chemistry, Physical

Calcium Molybdenum Bronze as a Stable High-Capacity Cathode Material for Calcium-Ion Batteries

Munseok S. Chae et al.

ACS APPLIED ENERGY MATERIALS (2020)

Article Chemistry, Multidisciplinary

Electrochemically Induced Metal-Organic-Framework-Derived Amorphous V2O5for Superior Rate Aqueous Zinc-Ion Batteries

Shenzhen Deng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Architecting a Stable High-Energy Aqueous Al-Ion Battery

Chunshuang Yan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Physical

Strategies for Dendrite-Free Anode in Aqueous Rechargeable Zinc Ion Batteries

Ziyi Cao et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Physical

Heteroatom Doping: An Effective Way to Boost Sodium Ion Storage

Yu Li et al.

ADVANCED ENERGY MATERIALS (2020)

Review Chemistry, Physical

Defect Engineering in Manganese-Based Oxides for Aqueous Rechargeable Zinc-Ion Batteries: A Review

Ting Xiong et al.

ADVANCED ENERGY MATERIALS (2020)

Article Chemistry, Physical

Machine learning assisted materials design and discovery for rechargeable batteries

Yue Liu et al.

ENERGY STORAGE MATERIALS (2020)

Article Energy & Fuels

Polypyrrole Wrapped V2O5Nanowires Composite for Advanced Aqueous Zinc-Ion Batteries

Xinghua Qin et al.

FRONTIERS IN ENERGY RESEARCH (2020)

Article Chemistry, Multidisciplinary

Shallow-layer pillaring of a conductive polymer in monolithic grains to drive superior zinc storage via a cascading effect

Zhenguo Yao et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Review Chemistry, Physical

Intercalation and exfoliation chemistries of transition metal dichalcogenides

Qingyong Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

Layered VSe2: a promising host for fast zinc storage and its working mechanism

Lili Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Article Chemistry, Physical

Catalyzing zinc-ion intercalation in hydrated vanadates for aqueous zinc-ion batteries

Chaofeng Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Physical

Scientific Challenges for the Implementation of Zn-Ion Batteries

Lauren E. Blanc et al.

Review Chemistry, Multidisciplinary

Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries

Feixiang Wu et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Reversible Oxygen Redox Chemistry in Aqueous Zinc-Ion Batteries

Fang Wan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

Reaction Mechanisms for Long-Life Rechargeable Zn/MnO2 Batteries

Yun Li et al.

CHEMISTRY OF MATERIALS (2019)

Article Chemistry, Multidisciplinary

Aqueous Zinc-Ion Storage in MoS2 by Tuning the Intercalation Energy

Hanfeng Liang et al.

NANO LETTERS (2019)

Article Chemistry, Physical

Persistent zinc-ion storage in mass-produced V2O5 architecture

Dong Chen et al.

NANO ENERGY (2019)

Article Chemistry, Multidisciplinary

A Superior δ-MnO2 Cathode and a Self-Healing Zn-δ-MnO2 Battery

Donghong Wang et al.

ACS NANO (2019)

Article Chemistry, Multidisciplinary

Achieving Both High Voltage and High Capacity in Aqueous Zinc-Ion Battery for Record High Energy Density

Longtao Ma et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Article Chemistry, Multidisciplinary

A High Capacity Bilayer Cathode for Aqueous Zn-Ion Batteries

Kaiyue Zhu et al.

ACS NANO (2019)

Article Chemistry, Multidisciplinary

Conformal Conducting Polymer Shells on V2O5 Nanosheet Arrays as a High-Rate and Stable Zinc-Ion Battery Cathode

Dongming Xu et al.

ADVANCED MATERIALS INTERFACES (2019)

Review Electrochemistry

Automotive Li-Ion Batteries: Current Status and Future Perspectives

Yuanli Ding et al.

ELECTROCHEMICAL ENERGY REVIEWS (2019)

Review Chemistry, Multidisciplinary

Issues and opportunities facing aqueous zinc-ion batteries

Boya Tang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Article Chemistry, Physical

Boosting the Zn-ion storage capability of birnessite manganese oxide nanoflorets by La3+ intercalation

Haozhe Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Physical

Defect engineering activating (Boosting) zinc storage capacity of MoS2

Wangwang Xu et al.

ENERGY STORAGE MATERIALS (2019)

Article Chemistry, Physical

Layered (NH4)2V6O16•1.5H2O nanobelts as a high-performance cathode for aqueous zinc-ion batteries

Xiao Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Article Chemistry, Physical

Ammonium Vanadium Oxide [(NH4)2V4O9] Sheets for High Capacity Electrodes in Aqueous Zinc Ion Batteries

Yifu Zhang et al.

ACS APPLIED ENERGY MATERIALS (2019)

Article Chemistry, Physical

PVP incorporated MoS2 as a Mg ion host with enhanced capacity and durability

Canlong Wu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Review Chemistry, Physical

Boosting the cycling stability of transition metal compounds-based supercapacitors

Teng Wang et al.

ENERGY STORAGE MATERIALS (2019)

Review Chemistry, Multidisciplinary

MXene as a Charge Storage Host

Masashi Okubo et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Multidisciplinary

Investigation of V2O5 as a low-cost rechargeable aqueous zinc ion battery cathode

Jiang Zhou et al.

CHEMICAL COMMUNICATIONS (2018)

Review Green & Sustainable Science & Technology

The lithium-ion battery: State of the art and future perspectives

Ghassan Zubi et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

Article Chemistry, Physical

Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High-Performance Zinc-Ion Batteries

Pan He et al.

ADVANCED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

How Water Accelerates Bivalent Ion Diffusion at the Electrolyte/Electrode Interface

Fei Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Li+ intercalated V2O5•nH2O with enlarged layer spacing and fast ion diffusion as an aqueous zinc-ion battery cathode

Yongqiang Yang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Article Chemistry, Multidisciplinary

Water-Activated VOPO4 for Magnesium Ion Batteries

Xiao Ji et al.

NANO LETTERS (2018)

Review Chemistry, Physical

Recent Advances in Aqueous Zinc-Ion Batteries

Guozhao Fang et al.

ACS ENERGY LETTERS (2018)

Article Chemistry, Physical

Layered MgxV2O5•nH2O as Cathode Material for High-Performance Aqueous Zinc Ion Batteries

Fangwang Ming et al.

ACS ENERGY LETTERS (2018)

Article Chemistry, Multidisciplinary

Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries

Y. Xie et al.

ENERGY & ENVIRONMENTAL SCIENCE (2017)

Review Chemistry, Multidisciplinary

Layer Structured Materials for Advanced Energy Storage and Conversion

Yanpeng Guo et al.

Article Chemistry, Physical

Layered VS2 Nanosheet-Based Aqueous Zn Ion Battery Cathode

Pan He et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Physical

Aqueous Mg-Ion Battery Based on Polyimide Anode and Prussian Blue Cathode

L. Chen et al.

ACS ENERGY LETTERS (2017)

Article Chemistry, Physical

A 3.4 V Layered VOPO4 Cathode for Na-Ion Batteries

Guang He et al.

CHEMISTRY OF MATERIALS (2016)

Article Chemistry, Multidisciplinary

Cation-Deficient Spinel ZnMn2O4 Cathode in Zn(CF3SO3)2 Electrolyte for Rechargeable Aqueous Zn-Ion Battery

Ning Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Chemistry, Multidisciplinary

Towards greener and more sustainable batteries for electrical energy storage

D. Larcher et al.

NATURE CHEMISTRY (2015)

Article Chemistry, Multidisciplinary

Energetic Zinc Ion Chemistry: The Rechargeable Zinc Ion Battery

Chengjun Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Metallic Few-Layered VS2 Ultrathin Nanosheets: High Two-Dimensional Conductivity for In-Plane Supercapacitors

Jun Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)