4.7 Article

Thermal characteristic and performance influence of a hybrid supercapacitor

期刊

JOURNAL OF ENERGY STORAGE
卷 53, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.est.2022.105188

关键词

Hybrid supercapacitor; Thermal characteristics; Cathode electrode thickness; Capacitance; Energy density

资金

  1. National Natural Science Foundation of China [51906219]
  2. Natural Science Foundation of Zhejiang Province [LQ21E060002, LQ21E060001, LQ21E060003]
  3. Science and Technology Planning Project of Ningbo Municipality [2019B10045]

向作者/读者索取更多资源

The working performance of hybrid supercapacitor was comprehensively studied, with a focus on the electrothermal coupling and thermal characteristics. The study found that ambient temperature, electrode thickness, and the thickness ratio of anode to cathode electrodes have significant impacts on the performance. Higher ambient temperature, greater charge-discharge current, and thicker cathode electrode lead to a more significant temperature rise. Low ambient temperature causes capacitance attenuation and an increase in equivalent series internal resistance. The sensitivity of the hybrid supercapacitor is affected by the cathode-electrode thickness, with an increase leading to longer charge-discharge time and lower average state of charge. The capacitance increases as the cathode-electrode thickness increases, resulting in improved average energy density. However, the power density decreases due to the simultaneous increase in equivalent series resistance and heat production.
The working performance of hybrid supercapacitor was comprehensively studied. The electrothermal coupling and thermal characteristics of hybrid supercapacitor were discussed. The influences of operation parameters, such as ambient temperature, electrode thickness, thickness ratio of anode to cathode electrodes were examined. The heat generation rate, temperature distribution and working performance of hybrid supercapacitor were analyzed during charge-discharge. The results show that a higher ambient temperature, a greater chargedischarge current, and a thicker cathode electrode will lead to much more obvious temperature rise. Consequently, the high-temperature accumulation effect on the central area of hybrid supercapacitor easily occurs. The low ambient temperature will cause capacitance attenuation, while the equivalent series internal resistance increases greatly. When the ambient temperature is the same, the cathode-electrode thickness will affect the sensitivity of a hybrid supercapacitor. The charge-discharge time increases with the increase of cathode electrode thickness, the average state of charge decreases with the increasing of cathode electrode thickness, the extraction-insertion of lithium ions are happened from the anode electrode, the capacitance of hybrid supercapacitor will finally increase. The average energy density can be significantly improved by increasing cathodeelectrode thickness. However, the equivalent series resistance and heat production simultaneously increase, so the power density decreases eventually.

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