4.7 Review

Atomic Layer Deposition Beyond Thin Film Deposition Technology

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Order of magnitude enhancement of inherently selective atomic layer deposition of zirconia on silicon without deposition on copper: The role of precursor

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Summary: This study reports the use of zirconium 2-methyl 2-butoxide (ZMB) and ethanol for zirconia atomic layer deposition (ALD), achieving high selectivity in depositing a uniform ZrO2 film on silicon. It was found that this method is at least 10 times more selective than using a different precursor for the deposition process.

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Next generation nanopatterning using small molecule inhibitors for area-selective atomic layer deposition

Josiah Yarbrough et al.

Summary: Area-selective atomic layer deposition (ALD) is a promising approach for nanofabrication, with the use of small molecule inhibitors (SMIs) as an alternative method to self-assembled monolayers (SAMs) for selective deposition. The focus is on better meeting the demands of high-volume device manufacturing and overcoming limitations of current methods.

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Impact of Ions on Film Conformality and Crystallinity during Plasma-Assisted Atomic Layer Deposition of TiO2

Karsten Arts et al.

Summary: This study demonstrates that even under low-energy ion conditions, ions have a significant impact on the conformality, film thickness, crystallinity, and wet etch rate of TiO2 films during plasma ALD. The magnitude of this impact depends on various parameters such as deposition temperature, plasma exposure time, and ion energy, which can be utilized to minimize or exploit the effect. Understanding the role of ions in plasma ALD is crucial for precise control over film properties and process reproducibility.

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Inherently Area-Selective Atomic Layer Deposition of SiO2 Thin Films to Confer Oxide Versus Nitride Selectivity

Jinseon Lee et al.

Summary: This study exploits the substrate-dependent selectivity of aminosilane precursors for oxides versus nitrides through chemo-selective adsorption. By performing AS-ALD of SiO2 on SiO2 substrates, it is possible to achieve inherent deposition selectivity of approximately 4nm using di(isopropylamino)silane as the precursor. Additionally, by implementing an ALD-etch supercycle, enhanced deposition selectivity greater than approximately 10nm can be achieved on both blanket- and patterned substrates.

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Understanding chemical and physical mechanisms in atomic layer deposition

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Mechanisms of Thermal Atomic Layer Etching

Steven M. George

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Molecular mechanisms of atomic layer etching of cobalt with sequential exposure to molecular chlorine and diketones

Mahsa Konh et al.

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From the Bottom-Up: Toward Area-Selective Atomic Layer Deposition with High Selectivity

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Atomic Layer Etching: Rethinking the Art of Etch

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Area-Selective Atomic Layer Deposition Using Si Precursors as Inhibitors

Rizwan Khan et al.

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Aziz I. Abdulagatov et al.

CHEMISTRY OF MATERIALS (2018)

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Reaction Mechanism of Area-Selective Atomic Layer Deposition for Al2O3 Nanopatterns

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Selective Deposition of Dielectrics: Limits and Advantages of Alkanethiol Blocking Agents on Metal-Dielectric Patterns

Fatemeh Sadat Minaye Hashemi et al.

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Effect of substrate composition on atomic layer deposition using self-assembled monolayers as blocking layers

Wenyu Zhang et al.

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A (2016)

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Room temperature plasma enhanced atomic layer deposition for TiO2 and WO3 films

Alexander Strobel et al.

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A (2016)

Article Chemistry, Multidisciplinary

Sequential Regeneration of Self-Assembled Monolayers for Highly Selective Atomic Layer Deposition

Fatemeh Sadat Minaye Hashemi et al.

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Article Materials Science, Multidisciplinary

Atomic Layer Etching at the Tipping Point: An Overview

G. S. Oehrlein et al.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2015)

Article Materials Science, Multidisciplinary

Atomic Layer Etching: What Can We Learn from Atomic Layer Deposition?

T. Faraz et al.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2015)

Article Materials Science, Multidisciplinary

Atomic Layer Etching: An Industry Perspective

Colin T. Carver et al.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY (2015)

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Peter De Bisschop

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Atomic Layer Deposition Assisted Pattern Multiplication of Block Copolymer Lithography for 5 nm Scale Nanopatterning

Hyoung-Seok Moon et al.

ADVANCED FUNCTIONAL MATERIALS (2014)

Article Electrochemistry

A Short History of Atomic Layer Deposition: Tuomo Suntola's Atomic Layer Epitaxy

Riikka L. Puurunen

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Hidetami Yaegashi et al.

ADVANCES IN RESIST MATERIALS AND PROCESSING TECHNOLOGY XXIX (2012)

Proceedings Paper Nanoscience & Nanotechnology

Etch Challenges for 1x nm NAND Flash

Myung Kyu Ahn et al.

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Atomic Layer Deposition: An Overview

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Etching of Nb2O5 Thin Films by NbCl5

Kjell Knapas et al.

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Editorial Material Engineering, Electrical & Electronic

The quantum limit to Moore's law

James R. Powell

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Chemistry for positive pattern transfer using area-selective atomic layer deposition

R Chen et al.

ADVANCED MATERIALS (2006)

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Low-temperature Al2O3 atomic layer deposition

MD Groner et al.

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Crystallization behavior of thin ALD-Al2O3 filMS

S Jakschik et al.

THIN SOLID FILMS (2003)

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Thin film atomic layer deposition equipment for semiconductor processing

O Sneh et al.

THIN SOLID FILMS (2002)