Unveiling the effect of annealing on magnetic properties of nanocrystalline half-metallic Heusler Co2FeSi alloy glass-coated microwires

In this article, we present a new Co2FeSi glass-coated microwire obtained by Taylor-Ulitovsky technique with nanocrystalline structure consisting of a mixture of bcc phase (lattice parameter, a = 5.640 angstrom, crystalline grain size, D-g = 17.8 nm) in as-prepared sample. The annealing temperature was fixed at 873 K, and the annealing time was 1 and 6 h. The annealing resulted in a significant increase of such nano-grains up to (31.6 nm). Perfect square hysteresis loops have been observed in all annealed samples at a wide temperature range (55-400 K) that are not seen in the as prepared sample. The thermal magnetic behavior for the annealed samples shows dramatic magnetic behavior at low temperature. Large irreversibility magnetic behavior with a blocking temperature (T-b = 150 K) has been observed for annealed sample for 1 h. Critical temperatures of 155 K and 105 K have been detected for annealed samples for 1 h and 6 h, respectively, where the behavior of M-H loops, coercivity and remanence changed. Below the critical point the M-H shows wasp-waisted, multistep magnetic behavior and complex magnetic reversal mechanism is supposed. The anomalous magnetic behavior is due to the coexistence of the ordered and disordered phases induced by annealing conditions below the room temperature. The difference in the magnetization behaviour, remanence, and coercivity values for Co2FeSi glass-coated microwires samples indicates the influence of internal stresses created by the presence of the glass coating. These finding opens the door to design spintronic devices based on the magnetization switching. (C) 2022 The Authors. Published by Elsevier B.V.

Automated summary

This article presents a new Co2FeSi glass-coated microwire with a nanocrystalline structure obtained using the Taylor-Ulitovsky technique. The annealing process significantly increased the size of the nanograins and resulted in the observation of perfect square hysteresis loops. The annealed samples exhibited dramatic magnetic behavior at low temperatures and showed critical temperature points where the magnetic behavior changed. The anomalous magnetic behavior can be attributed to the coexistence of ordered and disordered phases induced by annealing conditions. The presence of the glass coating influenced the magnetization behavior and mechanical properties of the Co2FeSi microwires.