期刊
FRONTIERS IN CHEMISTRY
卷 10, 期 -, 页码 -出版社
FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2022.1000337
关键词
MnOx; stability; cathode; interface; zinc ion battery
资金
- National Natural Science Foundation of China
- China Postdoctoral Science Foundation
- [52002122]
- [2021M690947]
This mini review summarizes the bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries, providing theoretical support for the design of manganese oxide cathode materials with high stability for aqueous zinc ion batteries.
The cyclic stability of the MnOx cathodes for rechargeable zinc ion batteries have substantial obstacles due to Mn3+ disproportionation produces Mn2+ caused by Jahn Teller lattice distortion effect in the process of Zn2+ inter/ deintercalation. This mini review summarized bulk-phase and interface stability strategies of manganese oxide cathodes for aqueous Zn-MnOx batteries from the regulation of bulk electronic state of manganese oxide improves its structural stability and the formation of beneficial SEI layer at the interface of electrolyte. It provides theoretical support for the design of manganese oxide cathode materials for aqueous zinc ion batteries with high stability.
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