Supramolecular Self-Assembly Strategy towards Fabricating Mesoporous Nitrogen-Rich Carbon for Efficient Electro-Fenton Degradation of Persistent Organic Pollutants

The electro-Fenton (EF) process is regarded as an efficient and promising sewage disposal technique for sustainable water environment protection. However, current developments in EF are largely restricted by cathode electrocatalysts. Herein, a supramolecular self-assembly strategy is adopted for synthetization, based on melamine-cyanuric acid (MCA) supramolecular aggregates integrated with carbon fixation using 5-aminosalicylic acid and zinc acetylacetonate hydrate. The prepared carbon materials characterize an ordered lamellar microstructure, high specific surface area (595 m(2) g(-1)), broad mesoporous distribution (4 similar to 33 nm) and high N doping (19.62%). Such features result from the intrinsic superiority of hydrogen-bonded MCA supramolecular aggregates via the specific molecular assembly process. Accordingly, noteworthy activity and selectivity of H2O2 production (similar to 190.0 mg L-1 with 2 h) are achieved. Excellent mineralization is declared for optimized carbon material in several organic pollutants, namely, basic fuchsin, chloramphenicol, phenol and several mixed triphenylmethane-type dyestuffs, with total organic carbon removal of 87.5%, 74.8%, 55.7% and 54.2% within 8 h, respectively. This work offers a valuable insight into facilitating the application of supramolecular-derived carbon materials for extensive EF degradation.

Automated summary

In this study, carbon materials with high activity and selectivity were synthesized using a supramolecular self-assembly strategy. These materials showed excellent mineralization performance in the treatment of various organic pollutants, highlighting the importance of supramolecular-derived carbon materials in EF degradation.