Influence of P Content on Microstructure and Texture Evolution of the Oxygen-Free Copper

The present work aims to systematically investigate the influence of P content on the microstructure and texture evolution of oxygen-free copper during intermediate annealing and final cold rolling. The microstructure and texture evolution were studied by electron backscattered diffraction and transmission electron microscopy. With the addition of P, the grains refined and a large fraction of low angle grain boundaries (LAGBs) emerged after intermediate annealing. The texture transformed from pure metal type for pure Cu to the alpha-fiber texture which included brass and Goss texture as P was added. The recrystallization temperature increased with the addition of P, and refined grains after the final cold rolling process. The addition of elemental P would reduce the stacking fault energy, and then influence the transformation of the deformation and recrystallization texture of the copper. Accompanied by the evolution of the deformation texture, the recrystallization cubic texture {001} was suppressed and a strong {236} brass recrystallization texture emerged with the addition of elemental P after the intermediate annealing and subsequent final cold rolling process.

Automated summary

This study systematically investigates the influence of P content on the microstructure and texture evolution of oxygen-free copper during intermediate annealing and final cold rolling. It is found that the addition of P can refine grains and lead to the emergence of low angle grain boundaries (LAGBs), as well as transform the texture of the copper. Furthermore, the recrystallization temperature increases with the addition of P, and the grains are further refined during the final cold rolling process. The addition of P also affects the deformation and recrystallization texture of the copper.