期刊
ADVANCED MATERIALS INTERFACES
卷 9, 期 36, 页码 -出版社
WILEY
DOI: 10.1002/admi.202201394
关键词
C; (60); cobalt; Gaq; (3); solid-state nuclear magnetic resonance (NMR); spinterfaces
资金
- EC [H2020-FET-OPEN-965046, H2020-FET-OPEN-964396]
- Consiglio Nazionale delle Ricerche within the CRUI-CARE Agreement
The hybridization of surface orbitals with molecular orbitals in thin ferromagnetic layers can modify the key magnetic parameters. This study investigates the effects of surface hybridization on magnetic properties and reveals the reconstruction of magnetic environment at the cobalt surface in polycrystalline films.
The hybridization of the surface orbitals of thin ferromagnetic layers with molecular orbitals represents a soft but efficient technology that is able to induce in ferromagnetic component radical modifications of the key magnetic parameters, such as magnetization, magnetic anisotropy, and others. These effects are investigated in 7 nm thick polycrystalline Co films interfaced with C-60 and Gaq(3) molecular layers by combining Co-59 Ferromagnetic nuclear resonance spectroscopy (FNR) and magneto-optic kerr effect (MOKE) techniques. It is demonstrated that the surface hybridization produces a significant magnetic hardening with respect to a reference Co/Al system and that the molecule-induced effects modify the magnetic properties of entire Co layer, propagating for several nm from the interface. The FNR spectroscopy also reveals a reconstruction of the magnetic environment at the cobalt surface, whose observation in polycrystalline films is especially intriguing. The results shed new and unexpected light on the interfacial physics in such systems, whose understanding necessitates further experimental and theoretical research.
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