4.8 Article

High-throughput identification of highly active and selective single-atom catalysts for electrochemical ammonia synthesis through nitrate reduction

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Engineering, Environmental

Promoting N2 electroreduction into NH3 over porous carbon by introducing oxygen-containing groups

Zhimin Song et al.

Summary: In this study, a porous carbon material with oxygen-containing groups was developed to enhance the yield rate and Faradaic efficiency of nitrogen electroreduction to ammonia. The introduction of oxygen-containing groups effectively lowered the energy barrier of hydrogenation and suppressed the competing hydrogen evolution reaction, thereby promoting nitrogen electroreduction to ammonia.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Chemistry, Physical

Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes

Zechao Zhuang et al.

Summary: This article investigates a reverse atom-trapping strategy to improve cathode performance in solid-oxide fuel cells by controlling the extraction of strontium atoms from the surface. The experimental results show that this strategy significantly increases the power density of single cells and improves the longevity of the cathode.

NATURE CATALYSIS (2022)

Article Chemistry, Physical

Tuning single metal atoms anchored on graphdiyne for highly efficient and selective nitrate electroreduction to ammonia under aqueous environments: A computational study

Meiqi Yang et al.

Summary: In this study, the potential of single transition metal atoms anchored on graphdiyne as electrocatalysts for nitrate reduction reaction to ammonia was explored using density functional theory computations. Os/GDY was identified as an ideal catalyst with low limiting potential and great suppressing effect on competing reactions. The catalytic activity of nitrate reduction reaction was rationalized based on the adsorption strength and polarized charge on the adsorbed NO3 * species.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Multidisciplinary

Dynamic coordination transformation of active sites in single-atom MoS2 catalysts for boosted oxygen evolution catalysis

Nian Ran et al.

Summary: This study presents a strategy for designing 3d transition metal-oxygen complex single-atom catalytic sites to achieve high catalytic activity for the oxygen evolution reaction (OER). Through a dynamic coordination transformation, the active sites and adsorption-responsive orbitals are exposed, favoring the adsorption of oxidative intermediates and improving the OER catalytic activity.

ENERGY & ENVIRONMENTAL SCIENCE (2022)

Article Chemistry, Multidisciplinary

Theoretical Insights into the Mechanism of Selective Nitrate-to-Ammonia Electroreduction on Single-Atom Catalysts

Huan Niu et al.

Summary: Selective nitrate-to-ammonia electrochemical conversion is an efficient pathway to solve nitrate pollution, and current research on single-atom catalysts demonstrates high efficiency and selectivity in NO3RR, paving the way for further development in this area.

ADVANCED FUNCTIONAL MATERIALS (2021)

Article Chemistry, Physical

Computational Screening of High Activity and Selectivity TM/g-C3N4 Single-Atom Catalysts for Electrocatalytic Reduction of Nitrates to Ammonia

Lingling Lv et al.

Summary: This study investigates the activity and selectivity of TM/g-C3N4 single-atom catalysts for NO3RR to NH3, with Ru/g-C3N4 identified as the most promising catalyst due to its lowest energy barrier and extraordinary selectivity. The origin of Ru/g-C3N4's activity is explained from the perspective of NO3- adsorption, while the hydrogen evolution reaction is found to be uncompetitive for H atom adsorption. This work provides a screening mechanism for new catalysts, promotes NO3RR development, and stimulates further experimental exploration.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

Article Multidisciplinary Sciences

Robust wrinkled MoS2/N-C bifunctional electrocatalysts interfaced with single Fe atoms for wearable zinc-air batteries

Yan Yan et al.

Summary: This study presents a facile strategy for crafting MoS2@Fe-N-C bifunctional electrocatalysts with enhanced ORR and OER performance, leading to robust wearable ZABs with high capacity and outstanding cycling stability. The single-atom-interfaced core/shell design shows lowered energy barriers for both reactions, resulting in efficient metal-air batteries.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2021)

Article Multidisciplinary Sciences

Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalyst

Zhen-Yu Wu et al.

Summary: The study reports a method for selectively converting nitrate to ammonia using an Fe single atom catalyst, which effectively prevents the formation of N-N coupling products while increasing the production rate of ammonia.

NATURE COMMUNICATIONS (2021)

Review Chemistry, Physical

Pyrolysis-free covalent organic framework-based materials for efficient oxygen electrocatalysis

Xun Cui et al.

Summary: Pyrolysis-free covalent organic frameworks (COFs) serve as a promising platform for oxygen electrocatalysis research, enabling the preservation of active sites and facilitating a deeper understanding of electrocatalytic mechanisms. Their tunable porosity, atomically precise structures, and programmable topological architectures make them ideal candidates for high-performance electrocatalysts.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

Article Chemistry, Multidisciplinary

Enhanced Nitrate-to-Ammonia Activity on Copper-Nickel Alloys via Tuning of Intermediate Adsorption

Yuhang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Physical

Nanostructured photocatalysts for nitrogen fixation

Guoqiang Zhang et al.

NANO ENERGY (2020)

Article Materials Science, Multidisciplinary

Non-noble metal single-atom catalysts with phosphotungstic acid (PTA) support: A theoretical study of ethylene epoxidation

Shamraiz Hussain Talib et al.

SCIENCE CHINA-MATERIALS (2020)

Article Chemistry, Physical

Theoretical Investigation of Single and Double Transition Metals Anchored on Graphyne Monolayer for Nitrogen Reduction Reaction

Lakshitha Jasin Arachchige et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Chemistry, Multidisciplinary

Intrinsic Activity of Metal Centers in Metal-Nitrogen-Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis

Chang Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Nanoscience & Nanotechnology

Theoretical Screening of Single Atoms Supported on Two-Dimensional Nb2CN2 for Nitrogen Fixation

Youchao Kong et al.

ACS APPLIED NANO MATERIALS (2020)

Article Multidisciplinary Sciences

Electrochemical synthesis of nitric acid from air and ammonia through waste utilization

Yuting Wang et al.

NATIONAL SCIENCE REVIEW (2019)

Editorial Material Chemistry, Physical

Electrochemical synthesis of ammonia as a potential alternative to the Haber-Bosch process

Grigorii Soloveichik

NATURE CATALYSIS (2019)

Article Nanoscience & Nanotechnology

Theoretical Investigation on the Single Transition-Metal Atom-Decorated Defective MoS2 for Electrocatalytic Ammonia Synthesis

Haoran Guo et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Review Chemistry, Multidisciplinary

Single atom electrocatalysts supported on graphene or graphene-like carbons

Huilong Fei et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Chemistry, Multidisciplinary

How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully

Cheng Tang et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Chemistry, Physical

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Bryan H. R. Suryanto et al.

NATURE CATALYSIS (2019)

Review Chemistry, Physical

Electrocatalytic reduction of nitrate: Fundamentals to full-scale water treatment applications

Sergi Garcia-Segura et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

Review Chemistry, Multidisciplinary

Heterogeneous single-atom catalysis

Aiqin Wang et al.

NATURE REVIEWS CHEMISTRY (2018)

Review Chemistry, Physical

Catalysts for nitrogen reduction to ammonia

Shelby L. Foster et al.

NATURE CATALYSIS (2018)

Review Chemistry, Physical

State-of-the-art and perspectives of the catalytic and electrocatalytic reduction of aqueous nitrates

Juan Martinez et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

Article Multidisciplinary Sciences

Molecular metal-N-x centres in porous carbon for electrocatalytic hydrogen evolution

Hai-Wei Liang et al.

NATURE COMMUNICATIONS (2015)

News Item Multidisciplinary Sciences

CHEMISTRY New recipe produces ammonia from air, water, and sunlight

Robert F. Service

SCIENCE (2014)

Article Chemistry, Physical

Adsorption of Ni, Pd, Pt, Cu, Ag and Au on the Fe3O4(111) surface

Xiaohu Yu et al.

SURFACE SCIENCE (2014)

Review Chemistry, Multidisciplinary

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

Xiao-Feng Yang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

Article Chemistry, Multidisciplinary

Ammonia synthesis using a stable electride as an electron donor and reversible hydrogen store

Masaaki Kitano et al.

NATURE CHEMISTRY (2012)

Article Chemistry, Multidisciplinary

Single-atom catalysis of CO oxidation using Pt1/FeOx

Botao Qiao et al.

NATURE CHEMISTRY (2011)

Review Chemistry, Multidisciplinary

Nitrogen Cycle Electrocatalysis

Victor Rosca et al.

CHEMICAL REVIEWS (2009)

Article Electrochemistry

Study of the electroreduction of nitrate on copper in alkaline solution

David Reyter et al.

ELECTROCHIMICA ACTA (2008)

Article Multidisciplinary Sciences

An Earth-system perspective of the global nitrogen cycle

Nicolas Gruber et al.

NATURE (2008)

Article Electrochemistry

Nitrate reduction on single-crystal platinum electrodes

GE Dima et al.

ELECTROCHIMICA ACTA (2005)

Article Electrochemistry

Trends in the exchange current for hydrogen evolution

JK Norskov et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2005)