Core-sheath structured porous carbon nanofiber composite anode material derived from bacterial cellulose/polypyrrole as an anode for sodium-ion batteries

A core-sheath structured carbon nanofiber@nitrogen-doped porous carbon (CNF@NPC) composite is synthesized as a promising anode material for sodium-ion batteries (SIBs). Particularly, the eco-friendly bacterial cellulose ( BC) is used as both template and precursor for the synthesis of CNF@NPC through the carbonization of bacterial cellulose@polypyrrole (BC@PPy). Due to the particular core-sheath structure and the synergetic effect between the CNF core layer and the NPC outer layer, the CNF@NPC exhibit outstanding electrochemical performance, including a high reversible specific capacity (240 mAh g(-1) at 100 mA g(-1) over 100 cycles), excellent rate performance (146.5 mAh g(-1) at 1000 mA g(-1)), and superior cycling stability (148.8 mAh g(-1) at 500 mA g(-1) over 400 cycles). The application of environmentally friendly electrode material may open a new situation for SIBs. (C) 2015 Elsevier Ltd. All rights reserved.