期刊
CHEMISTRYOPEN
卷 11, 期 9, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/open.202200104
关键词
aprotic solvent; cell wall effect; hydrogen donor; stable oligomer; wood lignin pyrolysis
资金
- Japan Society for the Promotion of Science [JP19H03019]
- JST-Mirai Program, Japan [JPMJMI20E3]
- China Scholarship Council (CSC)
In this study, pyrolysis of Japanese cedar wood was conducted using diphenoxybenzene and a hydrogen donor. The results showed that a thermally stable oligomer was obtained, and its yield increased with the degradation of cellulose at higher temperatures.
Pyrolysis of Japanese cedar wood in diphenoxybenzene (an aprotic solvent) with a hydrogen donor was investigated between 270-380 degrees C. Under these conditions, re-condensation via radical and quinone methide intermediates was efficiently suppressed and a thermally stable oligomer was obtained. The oligomer was stable even after the treatment time was extended. Yields of lignin-derived products at 270 degrees C were limited to approximately 20 wt %, but increased to >80 wt % (lignin basis) at the higher temperatures. The oligomer yield increased directly with the extent of the cellulose degradation at 350 degrees C. Based on the NMR analysis results, the ether bonds in lignin were largely cleaved, but condensed linkages such as beta-aryl and beta-beta and 5-5' types remained. The gamma-hydroxypropyl group was identified as a typical side chain, formed by hydrogenation of the double bond of a coniferyl alcohol-type structure.
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