4.6 Article

Design of Tannin-Based Poured Earth Material via Deflocculation-Coagulation Control: Additive Selection and Tannin Variation

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 10, 期 44, 页码 14495-14502

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.2c04078

关键词

poured earth; tannins; iron compounds; deflocculation-coagulation control; complexation

资金

  1. China Scholarship Council [201806090282]

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The study explores the use of natural tannin extracts and iron compounds to create poured earth material with higher strength and water resistance, paving the way for locally tailored solutions for circular and climate-neutral construction.
Combining the low environmental impact of vernacular earthen construction and the cost efficiency of the modern concrete pouring technique, poured earth is becoming more attractive for the construction sector nowadays. However, the development of poured earth is still in its infancy and few design options have been reported. In this study, we present a new type of poured earth based on natural tannin extracts and iron compounds. Tannin is used as a dispersant to liquefy clay materials, while the iron compound acts as an antitannin agent to slowly remove the dispersing effect and recoagulate clay. Specifically, iron compounds with different solubilities were selected and their complexation reaction kinetics with oak tannin were investigated through various techniques including UV-vis, ATR, o, and rheological measurements. Iron citrate was finally screened out because of its controlled speed of chelating tannin originating from various species with and without the presence of kaolinite. Such a study enables the production of a poured earth material based on natural additives with higher strength and water resistance. It paves the way for locally tailored solutions for circular and climate-neutral construction.

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