期刊
POLYMERS
卷 14, 期 19, 页码 -出版社
MDPI
DOI: 10.3390/polym14194153
关键词
thermoset; thermoset composites; recycling; polymer recycling
资金
- MIUR-Italy (Ministry of Education, University and Research of Italy) [CLEAN-PRIN-20174FSRZS_002]
Thermoset materials and their composites have important applications in aircraft, wind turbines, and constructions, and the interest in their recycling is growing. Successful recovery and valorization of these materials require degradation of their structures and recovery of valuable components. This mini-review focuses on the formulation and recovery methods of innovative thermoset materials with built-in recyclability. The aim is to provide an overview of thermoset recycling and commonly used composites, as well as novel formulating strategies. This review is also a valuable guide for students and technicians in polymer production and recycling.
Thermoset materials and their composites are characterized by a long life cycle with their main applications in aircrafts, wind turbines and constructions as insulating materials. Considering the importance of recovery and valorization of these materials at their end-of-life, avoiding landfilling, the interest concerning their recycling grows continuously. The thermoset materials and their composites, to be successfully recovered and valorized, must degrade their three-dimensional structures and recover the mono-oligomers and/or fillers. The thermoset materials could successfully degrade through thermal treatment at different temperatures (for example, above 1000 degrees C for incineration, ca. 500 degrees C for oxidation/combustion of organic constituents, etc.), chemical degradation by catalyst, irradiation with or without the presence of water, alcohol, etc., and mechanical recycling, obtaining fine particles that are useful as filler and/or reinforcement additives. Among these recycling methods, this mini-review focuses on the formulation and recovery method of innovative thermoset with in-build recyclability, i.e., materials having chemical links that could be degraded on-demand or containing dynamic covalent bonds to have re-processable and/or recyclable thermoset. This issue could be considered the future perspective in developing novel thermoset materials. The aim of this review is to get an overview of the state of the art in thermoset recycling and of the most commonly used thermoset composites, recovering valuable reinforcing fibers. Additionally, in this work, we also report not only known recycling routes for thermoset and thermoset-based composites, but also new and novel formulating strategies for producing thermosets with built-in recyclability, i.e., containing chemical-triggered on-demand links. This mini-review is also a valuable guide for educational purposes for students and specialized technicians in polymer production and recycling.
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