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Environmental Properties and Applications of Biodegradable Starch-Based Nanocomposites

POLYMERS (2022)

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Investigation of structural and physico-chemical properties of rice starch with varied amylose content: A combined microscopy, spectroscopy, and thermal study

Indira Govindaraju et al.

Summary: This study investigated the structural and functional characteristics of starch from ten indigenous rice varieties in Northeast India, showing variations in physicochemical properties and hydrolysis rates. Results revealed changes in starch granule shape during enzymatic hydrolysis and differences in starch crystallinity. Additionally, the research identified amylose hydrolysis and disturbances in the ordered arrangement in the crystalline part in hydrolyzed starch granules.

FOOD HYDROCOLLOIDS (2022)

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Article Biochemistry & Molecular Biology

The Functional and Application Possibilities of Starch/Chitosan Polymer Composites Modified by Graphene Oxide

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Summary: This study investigates the functional properties and degradation rate of bionanocomposites made of starch/chitosan/graphene oxide (GO) using a green synthesis method. It also explores the toxicity and effects on pathogenic microflora during storage of meat food products. The results indicate that the composites have weak barrier properties but are similar to biological systems. Chitosan-containing composites demonstrate good optical properties and high barrier performance, making them suitable for packaging applications. Additionally, the starch and chitosan films show relatively high biodegradability, lack toxicity, and provide a high barrier against many microorganisms, suggesting great potential for use in the food industry.

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES (2022)

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Summary: Protected cultivation in modern agriculture heavily relies on plastic-originated materials. However, the use of plastics can pose substantial threats to the geosphere, food security, and the environment. Mismanaged plastics in soil do not biodegrade and generate emerging pollutants. Therefore, the use of biodegradable polymers from renewable sources is a pragmatic solution for sustainable agricultural practices.

SUSTAINABILITY (2022)

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Review Polymer Science

Advanced Polymeric Nanocomposites for Water Treatment Applications: A Holistic Perspective

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Summary: This article introduces the synthesis and application of polymeric nanocomposites in water treatment, discusses the major criteria that influence their performance, and highlights the challenges and considerations for future research.

POLYMERS (2022)

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Article Food Science & Technology

Nanocellulose reinforced corn starch-based biocomposite films: Composite optimization, characterization and storage studies

Sharmila Patil et al.

Summary: Nanocellulose was used as a reinforcement to develop biocomposite films with improved functionality for storing edible oils. The composition of the films was optimized to enhance mechanical and barrier properties, resulting in a promising alternative packaging material.

FOOD PACKAGING AND SHELF LIFE (2022)

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Review Chemistry, Applied

Starch, cellulose, pectin, gum, alginate, chitin and chitosan derived (nano) materials for sustainable water treatment: A review

Mahmoud Nasrollahzadeh et al.

Summary: Natural biopolymers, such as cellulose, chitin/chitosan, and starch, are considered greener, sustainable, and eco-friendly materials due to their outstanding structural features, abundant availability, nontoxicity, and biocompatibility. In recent years, polysaccharides have been widely used for making various catalysts, with polysaccharides-supported metal/metal oxide materials being an effective strategy in nanotechnology. Polysaccharides adorned with nanomaterials have shown promising potential as efficient catalysts or sorbents in removing a variety of aqueous pollutants and contaminants.

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Does soluble starch improve the removal of Cr(VI) by nZVI loaded on biochar?

Chun Yang et al.

Summary: The novel material nZVI/SS/BC synthesized for the removal of hexavalent chromium from simulated wastewater showed promising results with the use of biochar pyrolyzed at 600 degrees Celsius and soluble starch during synthesis. The material exhibited high adsorption capacity, increased surface area, and improved removal efficiency.

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Summary: This study investigates the influence of different ionic surfactants on the dispersibility of multiwalled carbon nanotubes (MWNT) within a starch matrix. Films with MWNT-SC show the best dispersibility and have the highest tensile strength and Young's modulus, while MWNT-CTAB functionalization imparts the highest antioxidant activity and electrical conductivity to the starch matrix. The properties of starch-based films can be tailored based on the physical adsorption of each surfactant on MWNT surface and/or the interfacial interaction of the surfactant with starch chains.

CARBOHYDRATE POLYMERS (2021)

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Article Chemistry, Applied

Synergistic effects of starch nanoparticles and chitin nanofibers on the stability of oil-in-water Pickering emulsions

Yeong-Sheng Lee et al.

Summary: The study demonstrated that emulsions stabilized by a combination of SNPs and ChFs showed higher stability under different concentrations, storage times, and environmental conditions, especially when sonicated. The synergistic effect of using both SNPs and ChFs allowed for emulsion stabilization at lower solid nanoparticles concentrations than previously required.

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Significantly improved dielectric properties of bio-compatible starch/reduced graphene oxide nanocomposites

Shafiqul I. Mollik et al.

Summary: In this study, a bio-compatible plasticized starch/reduced graphene oxide (PS/rGO) nanocomposite was fabricated using a facile aqueous casting method. The structural properties and surface morphology of the nanocomposite were analyzed and revealed increased interaction between the PS matrix and rGO, along with improvements in optical absorbance, dielectric properties, and AC conductivity. The incorporation of rGO led to improved conductivity, reduced grain boundary resistance, and increased capacitance in the nanocomposite.

SYNTHETIC METALS (2021)

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Polysaccharide-based (nano)materials for Cr(VI) removal

Yasin Orooji et al.

Summary: Chromium is a potentially poisonous and carcinogenic species, particularly hexavalent chromium poses a significant threat to the environment and needs to be eliminated using methods like converting it to less toxic trivalent chromium. Biopolymers such as alginate and chitosan have received attention for their effectiveness in removing environmental pollutants, due to their advantageous properties like biodegradability and biocompatibility.

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In-vitro evaluation of thermoplastic starch/beta-tricalcium phosphate nano-biocomposite in bone tissue engineering

Marzieh Taherimehr et al.

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CERAMICS INTERNATIONAL (2021)

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Review Polymer Science

Review of the Most Important Methods of Improving the Processing Properties of Starch toward Non-Food Applications

Arkadiusz Zarski et al.

Summary: Starch, the second most abundantly available natural polymer in the world, is attractive for its biodegradability and non-toxicity, making it a popular raw material in food and non-food industries. However, due to its high hydrophilicity, complex processing operations are required, particularly in the packaging industry. With increasing awareness of the dangers of non-degradable petroleum polymers, there is a growing industry focusing on processing biodegradable materials for packaging purposes.

POLYMERS (2021)

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Summary: Biodegradable polymers (BP) are considered the materials of the future, with excellent properties comparable to commodity plastics. The lack of data on the durability of biodegradable polymer nanocomposites (BPN) has prompted a review summarizing recent literature data on environmental aging of BPN. Incorporating nanofillers into BP can improve durability, but poor dispersion may lead to faster degradation. Selected models describing the durability performance of BPN can be used to design materials with tailored degradation properties and durability.

POLYMERS (2021)

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Review Engineering, Environmental

Environmental performance comparison of bioplastics and petrochemical plastics: A review of life cycle assessment (LCA) methodological decisions

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Influence of the source of starch and plasticizers on the environmental burden of starch-Brazil nut fiber biocomposite production: A life cycle assessment approach

Pedro M. Rojas-Bringas et al.

Summary: In the face of the global plastic pollution crisis, bio-based polymers have been suggested as a potential alternative. Studies have shown that starch-based biocomposites have lower environmental impacts compared to conventional materials, with the type of starch and plasticizer significantly influencing production. Brazil nut fibers are highlighted as an eco-friendly and low-burden natural filler due to their easy processing and agricultural waste origin.

SCIENCE OF THE TOTAL ENVIRONMENT (2021)

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Article Food Science & Technology

Incorporation of Extracted Mucor indicus Fungus Chitin Nanofibers into Starch Biopolymer: Morphological, Physical, and Mechanical Evaluation

Bahador Bahrami et al.

Summary: Bio-nanocomposites based on starch were reinforced with different percentages of chitin nanofibers and compatibilized with glycerol. The presence of nanofibers significantly improved the mechanical properties of the material, but decreased the elongation at break and increased moisture absorption of the film.

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Teresa Russo et al.

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Effects of nanocellulose fiber and thymol on mechanical, thermal, and barrier properties of corn starch films

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Summary: The study found that the addition of NCF and thymol to CS films improved flexibility and thermal stability, but also affected mechanical and barrier properties.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2021)

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Chitin nanofiber-based nanocomposites containing biodegradable polymers for food packaging applications

Maryam Heidari et al.

Summary: The study focused on fabricating and characterizing ChNF-based nanocomposites with biodegradable polymers, such as thermoplastic starch, gelatin, and poly(vinyl alcohol). Mixing ChNF with polymers resulted in more homogeneous surfaces and improved crystalline properties. The nanocomposite films showed increased water vapor permeability compared to pure ChNF film, with varying water solubility values. Incorporating thermoplastic starch, gelatin, and poly(vinyl alcohol) led to enhanced physical and mechanical properties in the nanocomposites, making them potential materials for biodegradable and edible food packaging.

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Efficiency enhancement of slow release of fertilizer using nanozeolite-chitosan/sago starch-based biopolymer composite

Rungnapa Pimsen et al.

Summary: The study developed slow-release fertilizers using nanozeolite composite-chitosan/sago starch-based biopolymer, which showed promising results in improving growth indicators for Philodendron sp. The nanocomposite maintained water levels and exhibited potential for further use in agriculture as slow-release fertilizers.

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Functional Properties of Banana Starch (Musa spp.) and Its Utilization in Cosmetics

Norramon Thanyapanich et al.

Summary: The study utilized unripe banana fruit from two species grown in Thailand, extracting starches with different characteristics. The starches showed varying crystalline structures, good water and oil absorption capacities, and potential for use in powder base preparations without altering the sensory texture of the product.

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Effect of Amylose-Amylopectin Ratios on Physical, Mechanical, and Thermal Properties of Starch-Based Bionanocomposite Films Incorporated with CMC and Nanoclay

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Electroconductive starch/multi-walled carbon nanotube films plasticized by 1-ethyl-3-methylimidaz olium acetate

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Morphology and properties of thermoplastic starch blended with biodegradable polyester and filled with halloysite nanoclay

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CARBOHYDRATE POLYMERS (2020)

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Synergic antimicrobial properties of Carvacrol essential oil and montmorillonite in biodegradable starch films

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A novel pH-sensitive and magnetic starch-based nanocomposite hydrogel as a controlled drug delivery system for wound healing

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Amylose content and specific fine structures affect lamellar structure and digestibility of maize starches

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Starch-g-poly(acrylic acid-co-acrylamide) composites reinforced with natural char nanoparticles toward environmentally benign slow-release urea fertilizers

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Structural and Thermal Properties of Agricultural Mulch Films Based on Native and Oxidized Corn Starch Nanocomposites

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Graphene modifies the biodegradation of poly(lactic acid)-thermoplastic cassava starch reactive blend films

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Starch based nanofibrous scaffolds for wound healing applications

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Metal Oxide Nanostructures in Food Applications: Quality Control and Packaging

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Barrier and biodegradable properties of corn starch-derived biopolymer film filled with nanoclay fillers

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Green synthesis of Ag-Au bimetallic nanocomposites using a biodegradable synthetic graft copolymer; hydroxyethyl starch-g-poly (acrylamide-co-acrylic acid) and evaluation of their catalytic activities

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Effect of starch type on the physico-chemical properties of edible films

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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2017)

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Nanocomposites based on banana starch reinforced with cellulose nanofibers isolated from banana peels

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JOURNAL OF COLLOID AND INTERFACE SCIENCE (2017)

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Article Engineering, Environmental

Environmental impact assessment of six starch plastics focusing on wastewater-derived starch and additives

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RESOURCES CONSERVATION AND RECYCLING (2017)

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Interface modified polylactic acid/starch/poly ε-caprolactone antibacterial nanocomposite blends for medical applications

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Nano CaCO3 imprinted starch hybrid polyethylhexylacrylate\polyvinylalcohol nanocomposite thin films

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CARBOHYDRATE POLYMERS (2016)

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Review Biochemistry & Molecular Biology

Polysaccharide based bionanocomposites, properties and applications: A review

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Modification of physicochemical and thermal properties of starch films by incorporation of TiO2 nanoparticles

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Biodegradation behavior of starch-PVA films as affected by the incorporation of different antimicrobials

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POLYMER DEGRADATION AND STABILITY (2016)

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Impact of amylose content on starch physicochemical properties in transgenic sweet potato

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CARBOHYDRATE POLYMERS (2015)

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Effect of modified starch and nanoclay particles on biodegradability and mechanical properties of cross-linked poly lactic acid

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CARBOHYDRATE POLYMERS (2015)

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Physicochemical properties of starches from diverse rice cultivars varying in apparent amylose content and gelatinisation temperature combinations

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FOOD CHEMISTRY (2015)

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Fast dye removal from water by starch-based nanocomposites

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JOURNAL OF COLLOID AND INTERFACE SCIENCE (2015)

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Water barrier properties of starch films reinforced with cellulose nanocrystals obtained from sugarcane bagasse

Anibal M. Slavutsky et al.

CARBOHYDRATE POLYMERS (2014)

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Effect of potassium sorbate on antimicrobial and physical properties of starch-clay nanocomposite films

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Antimicrobial activity of silver/starch/polyacrylamide nanocomposite

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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2014)

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Review Chemistry, Applied

Preparation and application of starch nanoparticles for nanocomposites: A review

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REACTIVE & FUNCTIONAL POLYMERS (2014)

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Physicochemical and morphological characterization of different starches with variable amylose/amylopectin ratio

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FOOD HYDROCOLLOIDS (2013)

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Comparative Sustainability Assessment of Starch Nanocrystals

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JOURNAL OF POLYMERS AND THE ENVIRONMENT (2013)

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Nanocellulose: a new ageless bionanomaterial

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MATERIALS TODAY (2013)

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Biodegradable starch based nanocomposites with low water vapor permeability and high storage modulus

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CARBOHYDRATE POLYMERS (2012)

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Preparation and properties of novel melt-blended halloysite nanotubes/wheat starch nanocomposites

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CARBOHYDRATE POLYMERS (2012)

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Green synthesis and characteristic of core-shell structure silver/starch nanoparticles

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MATERIALS LETTERS (2011)

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Starch-based composites reinforced with novel chitin nanoparticles

Peter R. Chang et al.

CARBOHYDRATE POLYMERS (2010)

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Relationship of Granule Size Distribution and Amylopectin Structure with Pasting, Thermal, and Retrogradation Properties in Wheat Starch

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JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY (2010)

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Starch-based completely biodegradable polymer materials

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EXPRESS POLYMER LETTERS (2009)

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Form and functionality of starch

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FOOD HYDROCOLLOIDS (2009)

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Can nanotechnology improve the sustainability of biobased products? The case of layered silicate biopolymer nanocomposites

Satish Joshi

JOURNAL OF INDUSTRIAL ECOLOGY (2008)

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Review Engineering, Environmental

Life Cycle Assessment of Polysaccharide Materials: A Review

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JOURNAL OF POLYMERS AND THE ENVIRONMENT (2008)

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Environmental systems analysis tools - an overview

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Alternative tissue engineering scaffolds based on starch: processing methodologies, morphology, degradation and mechanical properties

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MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS (2002)

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Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials

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