期刊
CARBON
卷 90, 期 -, 页码 44-52出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2015.03.066
关键词
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资金
- National Science Foundation for Fostering Talents in Basic Research of the National Natural Science Foundation of China [J1103307]
- Basic Scientific Research Business Expenses of the Central University and Open Project of Key Laboratory for Magnetism and Magnetic Materials of the Ministry of Education, Lanzhou University [LZUMMM2014001, LZUMMM2014014]
- Fundamental Research Funds for the Central University [lzujbky-2014-189]
- Science and Technology Program of Gansu Province of China [145RJZA176]
In this work, three dimensional (3D) NixCo1-xS2/graphene composite hydrogels with different Ni contents (denoted as NixCo1-xS2/GH (x = 0, 0.31, 0.56, 0.66, 1)) have been synthesized by a simple one-step hydrothermal method and utilized as the active materials of supercapacitors. The as-prepared samples present a 3D interconnected porous network with the pore sizes in the range of several to tens micrometers. Interestingly, the NixCo1-xS2 particles are uniformly located on the graphene network and the particle size is evolved from similar to 50 nm to similar to 1.5 mu m with the increase of Ni content. The electrochemical measurements revealed that the specific capacitance, rate capability and cyclability of different NixCo1-xS2/GH electrodes are strongly affected by their different Ni content. Among these, the 3D Ni0.31Co0.69S2/GH composite has the highest specific capacitance of 1166 F/g at a current density of 1 A/g. Furthermore, a specific capacitance of 559 F/g can be still maintained at high current density of 20 A/g. After 1000 charge-discharge cycles at 5 A/g, the specific capacitance remains a high value of 755 F/g. (C) 2015 Elsevier Ltd. All rights reserved.
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