Dispersive transport dynamics in porous media emerge from local correlations

Dispersive transport through complex media, relevant for semiconductors, liquid crystals, and biological soft matter, is influenced by their microscopic, porous structure. The authors consider the statistics of pore-junction units, in contrast to individual pores, to link morphology and macroscopic transport characteristics. Understanding and controlling transport through complex media is central for a plethora of processes ranging from technical to biological applications. Yet, the effect of micro-scale manipulations on macroscopic transport dynamics still poses conceptual conundrums. Here, we demonstrate the predictive power of a conceptual shift in describing complex media by local micro-scale correlations instead of an assembly of uncorrelated minimal units. Specifically, we show that the non-linear dependency between microscopic morphological properties and macroscopic transport characteristics in porous media is captured by transport statistics on the level of pore junctions instead of single pores. Probing experimentally and numerically transport through two-dimensional porous media while gradually increasing flow heterogeneity, we find a non-monotonic change in transport efficiency. Using analytic arguments, we built physical intuition on how this non-monotonic dependency emerges from junction statistics. The shift in paradigm presented here broadly affects our understanding of transport within the diversity of complex media.

Automated summary

This study investigates dispersive transport through complex media and reveals the nonlinear dependence between microscopic morphology and macroscopic transport characteristics by studying the statistics of pore-junction units. It is of great significance for understanding and controlling transport in complex media.