期刊
JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE
卷 25, 期 3, 页码 1157-1162出版社
SPRINGER
DOI: 10.1007/s11665-016-1917-7
关键词
corrosion; inorganic coatings; magnesium; plasma electrolytic oxidation
资金
- Deutsche Forschungsgemeinschaft (DFG) [La-1274/34-1]
Plasma electrolytic oxidation (PEO) is a common means for the surface modification of light metals. However, PEO of magnesium substrates in dilute electrolytes generally leads to the formation of coatings consisting of unfavorable MgO magnesium oxide. By incorporation of electrolyte components, the phase constitution of the oxide coatings can be modified. Coatings consisting exclusively of MgAl2O4 magnesium-aluminum spinel are produced by PEO in an electrolyte containing hydroxide, aluminate, and phosphate anions. The hardness of the coatings is 3.5 GPa on Martens scale on average. Compared to the bare substrate, the coatings reduce the corrosion current density in dilute sodium chloride solution by approx. one order of magnitude and slightly shift the corrosion potential toward more noble values.
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