Introduction of oxygen vacancy to manganese ferrite by Co substitution for enhanced peracetic acid activation and 1O2 dominated tetracycline hydrochloride degradation under microwave irradiation

High microwave-response cobalt-substituted manganese ferrite (CMFO-0.5) was successfully synthesized as a heterogeneous catalyst for efficient peracetic acid (PAA) activation and tetracycline hydrochloride (TCH) degradation with singlet oxygen (O-1(2)) as the dominated reactive oxidized species (ROS). The removal efficiency of TCH could reach 98.16% within 6 min under microwave irradiation when the CMFO-0.5 was added at 20 mg/ L. It's found that the Co substitution could produce the oxygen vacancies (OVs), improve the microwave (MW) absorbing performance and enhance the internal electron transfer efficiency of materials. The phenomenon why O-1(2) as the dominated ROS rather than hydroxyl radical (center dot OH) and organic radicals (R-O center dot) would be explained by the following aspects: the oxygen adsorbed on the OVs can accept the electron transformed from PAA to form superoxide radical (center dot O-2(-) ), which will disproportionate to form O-1(2); the energy generated by the non-thermal effect of MW can dissociate PAA to generate peroxy-group for O-1(2) generation. Furthermore, the possible TCH degradation pathways were proposed based on DFT theory calculations and product identification, and the toxicity predictions of the degradation products were also performed by the Ecological Structure-Activity Relationship Model (ECOSAR) software. Additionally, the decrease of acute toxicity of treated TCH, excellent stability and strong resistance towards water matrix fully demonstrate the superiority of the proposed system for practical application in wastewater treatment.

Automated summary

High microwave-response cobalt-substituted manganese ferrite is successfully synthesized as a catalyst for peracetic acid activation and tetracycline hydrochloride degradation. The cobalt substitution improves microwave absorption performance and enhances the internal electron transfer efficiency. This system shows great potential for wastewater treatment.