4.4 Article

Co-deposited CuNi@MWCNTs nanocomposites for structural applications: tribo-mechanical and anti-corrosion performances

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TAYLOR & FRANCIS LTD
DOI: 10.1080/00202967.2022.2127512

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MWCNTs; CuNi; electrodeposition; powder technology; microstructure

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In this study, multi-walled carbon nanotube (MWCNT) reinforced copper-nickel alloy nanocomposites were synthesized and their microstructure, mechanical properties, and anti-corrosion performance were investigated.
In the present work, multi-walled carbon nanotube (MWCNT) nanofiller reinforced copper-nickel alloy (CuNi@MWCNTs) nanocomposites were synthesised by a modified electro-chemical co-deposition followed by compaction and sintering. During this method, CuNi@MWCNTs were co-deposited on a cathode tip at room temperature and collected from the electro-chemical bath in powdered form. Subsequently, the powdered nanocomposites were dried, compacted and sintered to prepare solid pellets. The influence of different amounts (25, 50 and 100 mg L-1) of MWCNT nanofillers in the deposition bath on microstructure, mechanical and anti-corrosion properties of CuNi@MWCNTs nanocomposites was investigated. The microhardness, compressive yield strength and friction coefficient of CuNi@MWCNTs (100 mg L-1) nanocomposites were enhanced by 45.7%, 37.2% and 55.1%, respectively, compared to that of pure CuNi alloy. In addition, the CuNi@MWCNTs nanocomposites obtained also exhibited improved anti-corrosion property in 3.5 wt.% NaCl solution at continuous agitation of 150 rpm and 27 degrees C temperature. Based on the research outcomes, this approach for synthesising CuNi@MWCNTs nanocomposites may be proposed for scale-up industrial trials.

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