期刊
TETRAHEDRON LETTERS
卷 111, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2022.154207
关键词
Diazotization reaction; P-H bonds; Transition-metal free synthesis; Aryl diazonium tetrafluoroborates
资金
- National Natural Science Foundation of China [21606080, 21908050]
- Open Project of Hunan Provincial Key Laboratory [HNPCCS201905]
- Scientific Research Fund of the Hunan Provincial Education Department [19B246]
- Innovation Research Group Project of the Natural Science Foundation of Hunan Province [2020JJ1004]
- CAS-Croucher Funding Scheme for Joint Laboratories
- ITC Guangdong-Hong Kong Technology Cooperation Funding Scheme (TCFS) [GHP/038/19GD]
- RGC Senior Research Fellowship Scheme [SRFS 2021-5S01]
- Research Institute for Smart Energy (CDAQ)
- Endowed Professorship in Energy from Miss Clarea Au [847S]
A pyridine-promoted diazotization of P-H bonds with aryl diazonium tetrafluoroborates is reported. The method is simple and efficient, providing azo organophosphorus compounds with excellent yields. It avoids the need for complex and harsh reaction conditions and the addition of oxides, and is tolerant to various functional groups. The synthesized azo organophosphorus compounds may find potential applications in organic chemistry and drug design.
A pyridine-promoted diazotization of P-H bonds with aryl diazonium tetrafluoroborates is established. The reported method is simple and efficient for the synthesis of azo organophosphorus compounds with excellent yields, which avoids the adoption of complex and harsh reaction conditions and the addition of oxides, tolerating various kinds of functional groups. The synthesized azo organophosphorus compounds may have potential applications in organic chemistry and drug design.(c) 2022 Elsevier Ltd. All rights reserved.
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