期刊
TETRAHEDRON LETTERS
卷 110, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2022.154176
关键词
Iron(II) catalyst; Alkylsilyl peroxides; Radical; Quaternary carbon
资金
- National Natural Science Foundation of China [22101053, 21977019, 22050410279]
- JSPS KAKENHI [JP21H05026]
A novel approach for constructing alpha-quaternary carbon centers using an Fe(II)-catalyzed alkylation reaction between alpha-alkoxy-1,3 dicarbonyl compounds and various alkylsilyl peroxides has been developed. This strategy enables the use of a broad range of 1,3 dicarbonyl derivatives and alkylsilyl peroxides as substrates, and involves a radical-promoted reaction pathway.
A novel approach for the construction of alpha-quaternary carbon centers by an Fe(II)-catalyzed alkylation of alpha-alkoxy-1,3 dicarbonyl compounds with various alkylsilyl peroxides has been developed. This strategy accommodates a broad substrate scope of 1,3 dicarbonyl derivatives and alkylsilyl peroxides via a radical-promoted reaction pathway. (C) 2022 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据