期刊
SYNTHESIS-STUTTGART
卷 55, 期 2, 页码 193-231出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1946-0512
关键词
photoinduced hydrogen-atom transfer (HAT); proton-coupled electron transfer (PCET); electron donor-acceptor (EDA) complex; excited-state transition-metal catalysis; dual catalysis; consecutive photoinduced electron transfer (conPET); excited radical ion photocatalysis (e-PRC); triplet-triplet annihilation upconversion; two-photon mechanisms; red and near-infrared (NIR) photocatalysis
This paper provides an overview of the development and application of visible light photocatalysis, and introduces some lesser-known modes of photochemical activation of organic molecules and emerging techniques in this field.
Visible light photocatalysis has evolved into a promising mild and sustainable strategy to access radicals. This field unlocks formerly challenging or even previously inaccessible organic transformations. In this review, an overview of some lesser-known modes of photochemical activation of organic molecules and several emerging techniques within the versatile field of visible light photocatalysis are discussed. These are illustrated by selected photocatalytic reactions, with particular attention given to the reaction mechanism. 1 Introduction 2 Advanced Photoactivation Modes 2.1 Photoinduced Hydrogen-Atom Transfer 2.2 Proton-Coupled Electron Transfer 2.3 Electron Donor-Acceptor Photoactivation of Organic Substrates 2.4 Excited-State Transition Metal Catalysis 3 Emerging Techniques 3.1 Dual Catalysis 3.2 Excited Radical Ion Photocatalysis 3.3 Upconversion Strategies and Other Two-Photon Mechanisms 3.4 Red and Near-Infrared Photocatalysis 4 Conclusions and Outlook
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