4.4 Article

Ultralong C(sp3)-C(sp3) Single Bonds Shortened and Stabilized by London Dispersion

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Computational Chemistry as a Conceptual Game Changer: Understanding the Role of London Dispersion in Hexaphenylethane Derivatives (Gomberg Systems)

Soeren Roesel et al.

Summary: This article provides a personal perspective on the history of hexaphenylethane (HPE) and its derivatives, discussing both the successful and unsuccessful attempts at interpreting experimental and computational data. The study of HPE has played a significant role in the development of chemical theory, advancing concepts such as mesomeric resonance and challenging traditional views on substituent effects. Understanding the stability and instability of HPE and its derivatives has important implications for the appreciation of London dispersion forces and the analytical power of computational chemistry.

ISRAEL JOURNAL OF CHEMISTRY (2022)

Article Chemistry, Multidisciplinary

London Dispersion Interactions Rather than Steric Hindrance Determine the Enantioselectivity of the Corey-Bakshi-Shibata Reduction

Christian Eschmann et al.

Summary: The well-known Corey-Bakshi-Shibata (CBS) reduction is a powerful method for the asymmetric synthesis of alcohols, with London dispersion (LD) interactions playing a crucial role in determining enantiodiscrimination. By modifying CBS catalysts with dispersion energy donors (DEDs), it was possible to improve catalyst design for challenging CBS reductions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Intramolecular London Dispersion Interactions Do Not Cancel in Solution

Jan M. Schuemann et al.

Summary: A comprehensive experimental study was conducted on a molecular balance to measure the effect of different solvents on the equilibrium of folded versus unfolded isomers. The study revealed that London dispersion interactions enthalpically favor the folded state in any measured solvent.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Could London Dispersion Force Control Regioselective (2+2) Cyclodimerizations of Benzynes? YES: Application to the Synthesis of Helical Biphenylenes

Takashi Ikawa et al.

Summary: In recent years, it has been discovered that London dispersion interactions play an important role in controlling the regio- and stereo-selectivity of reactions. These interactions are dominant in selective catalysis, while repulsive steric interactions are predominant in noncatalytic reactions. A novel method utilizing London dispersion interactions has been developed for the synthesis of proximal biphenylenes, which have potential applications in ligands, catalysts, and medicines.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Flexible C-C Bonds: Reversible Expansion, Contraction, Formation, and Scission of Extremely Elongated Single Bonds

Takuya Shimajiri et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Longest C-C Single Bond among Neutral Hydrocarbons with a Bond Length beyond 1.8 angstrom

Yusuke Ishigaki et al.

Article Chemistry, Multidisciplinary

Probing the Delicate Balance between Pauli Repulsion and London Dispersion with Triphenylmethyl Derivatives

Soeren Roesel et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Sizing the role of London dispersion in the dissociation of all-meta tert-butyl hexaphenylethane

Soeren Roesel et al.

CHEMICAL SCIENCE (2017)

Article Chemistry, Multidisciplinary

Distance-Dependent Attractive and Repulsive Interactions of Bulky Alkyl Groups

Jungwun Hwang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Stable Alkanes Containing Very Long Carbon-Carbon Bonds

Andrey A. Fokin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Steric Crowding Can Stabilize a Labile Molecule: Solving the Hexaphenylethane Riddle

Stefan Grimme et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Multidisciplinary

Synthesis of 1,8-di(1-adamantyl)naphthalenes as single enantiomers stable at ambient temperatures

Haruo Aikawa et al.

CHEMICAL COMMUNICATIONS (2011)

Article Chemistry, Physical

NCIPLOT: A Program for Plotting Noncovalent Interaction Regions

Julia Contreras-Garcia et al.

JOURNAL OF CHEMICAL THEORY AND COMPUTATION (2011)

Article Multidisciplinary Sciences

Overcoming lability of extremely long alkane carbon-carbon bonds through dispersion forces

Peter R. Schreiner et al.

NATURE (2011)

Article Chemistry, Multidisciplinary

Chiral Bronsted Acid-Catalyzed Allylboration of Aldehydes

Pankaj Jain et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Biochemistry & Molecular Biology

Strong and weak hydrogen bonds in the protein-ligand interface

Sunil K. Panigrahi et al.

PROTEINS-STRUCTURE FUNCTION AND BIOINFORMATICS (2007)

Review Chemistry, Multidisciplinary

Quantifying intermolecular interactions: Guidelines for the molecular recognition toolbox

CA Hunter

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Article Chemistry, Multidisciplinary

Helical rosette nanotubes: Design, self-assembly, and characterization

H Fenniri et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)