MXene-Derived Metal-Organic Framework@MXene Heterostructures toward Electrochemical NO Sensing

The electrochemical sensing of nitric oxide (NO) molecules by metal-organic framework (MOF) catalysts has been impeded, to a large extent, owing to their poor electrical conductivity and weak NO adsorption. In this work, incomplete in situ conversion of V2CTx (T = terminal atoms) MXene to MOF is adopted, forming MOF@MXene heterostructures, which outperform MXene and MOF monocomponents toward electrochemical NO sensing. Density functional theory (DFT) calculation results indicate metal-like electronic characters for the heterostructure benefiting from the dominating contribution of the V 3d orbitals of the metallic MXene. Moreover, plane-averaged charge density difference shows substantial charge redistribution occurs at the heterointerfaces, producing a built-in field, which facilitates charge transfer. Besides, molecular mechanics-based simulated annealing calculation reveals greatly enhanced adsorption energies of NO molecules on the heterointerfaces than that on separate MOFs and MXenes. Hence, the facilitated charge transfer and preferential NO adsorption are responsible for the dramatically promoted performance toward NO sensing. The prudent design of MOF@MXene heterostructure may spur advanced electrocatalysts for electrochemical sensing.

Automated summary

In this study, a novel method of incomplete in situ conversion was used to form MOF@MXene heterostructures, which significantly improved the electrochemical sensing performance of metal-organic framework (MOF) catalysts towards nitric oxide (NO) molecules. Density functional theory and molecular mechanics calculations revealed the metal-like electronic properties and enhanced NO adsorption energies of the heterostructures. This research may promote the development of advanced electrochemical sensing technologies.