期刊
CARBON
卷 87, 期 -, 页码 193-205出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2015.02.025
关键词
-
资金
- National High Technology Research and Development Program of China (863 Program) [2012AA06A304]
- National Science Foundation of China [21177044, 21377169, 21471122]
- Scientific Research Key Project of Hubei Provincial Department of Education (China) [D20121503]
- Natural Science Foundation of Hubei Province (China) [2012FFB04702]
Surface-enhanced Raman scattering (SERS) substrates with high SEAS activity and stability are important for SERS sensors. A facile method was developed to fabricate efficient and stable SERS substrates by combining Ag nanoparticles (NPs) and micro-scale sheeted graphitic carbon nitride (g-C3N4). The g-C3N4/Ag NPs hybrid could provide a great number of hot spots and concentrated the analyte by the pi-pi stacking interaction between analyte molecules and g-C3N4, making a dramatic Raman enhancement. Moreover, the g-C3N4/Ag NPs hybrid uniformly immobilized Ag NPs on the surface and edges of g-C3N4 sheets by an interaction between Ag NPs and g-C3N4, leading to much improved long-term stability. This could be explained in terms of the electron-donor effect of g-C3N4, which was further confirmed by density functional theory calculations. The inherent Raman enhancing effect of g-C3N4 itself also contributed to the total SERS responses. Due to multiple enhancement contributions, the g-C3N4/Ag NPs hybrid exhibited a strong Raman enhancement effect for with an enhancement factor of 4.6 x 10(8) (evaluated by using crystal violet as a probe), and possessed wide adaptability from dyes, pesticides to bio-molecules. (C) 2015 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据