Occurrence, concentration, and distribution of 38 organic micropollutants in the filter material of 12 stormwater bioretention facilities

The increased use of bioretention facilities as a low impact development measure for treating stormwater runoff under-scores the need to further understand their long-term function. Eventually, bioretention filter media must be (partly) re-placed and disposed of at the end of its functional lifespan. While there are several studies of metal accumulation and distributions in bioretention media, less is known about organic pollutant pathways and accumulation in these filters. The present study considers the occurrence and accumulation of 16 polycyclic aromatic hydrocarbons, 7 polychlorinated biphenyls, 13 phthalates, and two alkylphenols throughout 12 older bioretention facilities (7-13 years old) used for stormwater treatment in Michigan and Ohio, USA. These pollutant groups appear to behave similarly, with greater in-stances of detection and higher concentrations in the upper media layers which decrease with increased depth from the surface. The patterns of detection and concentration in the filter material may be explained by characteristics of the pollutants, such as molecular structures and solubility that affect the removal of the organic pollutants by the filter material. There is also a large variation in concentration magnitudes between the bioretention sites, most likely due to differences in pollutant sources, contributing catchment size and/or land uses.

Automated summary

The study investigates the occurrence and accumulation of organic pollutants in older bioretention facilities used for stormwater treatment. The results show that these pollutants tend to accumulate in the upper media layers of the filter material and their concentrations decrease with depth. The variation in pollutant concentrations between different sites is likely due to differences in pollutant sources and land uses.