期刊
JOURNAL OF LUMINESCENCE
卷 179, 期 -, 页码 393-401出版社
ELSEVIER
DOI: 10.1016/j.jlumin.2016.07.007
关键词
Ratiometric sensing; ESIPT; 3-hydroxy-4-quinolone; Micellar medium
类别
资金
- CONACYT
- DGAPA-UNAM
2-Phenyl-3-hydroxy-4(1H)-quinolone possessing dual fluorescence due to excited-state intramolecular proton transfer (ESIPT) forms stable complex with phenylboronic acid with blue shifted emission maximum in micellar medium of a cationic surfactant even though the compound lacks required for complexation with boronic acids cis-diol structure. No complexation is observed in the presence of neutral or anionic surfactants. Titrations of this complex with polyols including sugars and nucleotides at pH 8 displace free quinolone showing ratiometric response, which allows determination of polyols with detection limits 0.05-1 mM and unusually wide linear dynamic ranges. Another ESIPT dye 2-(2'-hydroxyphenyl)-1H-benzimidazole also lacking cis-diol structure forms equally stable complex with phenylboronic acid and allows ratiometric determination of polyols with similar characteristics. The results of this study demonstrate that blocking ESIPT of signaling molecule by complexation of the receptor with the proton donor group eliminates the low energy emission from tautomeric form but strongly enhances the high energy emission typical for normal form of signaling molecule creating a possibility of ratiometric sensing. (C) 2016 Elsevier B.V. All rights reserved.
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