A detailed high-pressure oxidation study of di-isopropyl ether

The oxidation of di-isopropyl-ether (DIPE) was studied in a jet-stirred reactor. Fuel-lean, stoichiometric, and fuel-rich mixtures ( & phi; = 0.5-4) were oxidized at a constant fuel mole fraction of 1000 ppm, at temperatures ranging from 500 to 1160 K, at 10 atm, and constant residence time of 0.7 s. The chosen conditions are consistent with our previous studies on ether oxidation. Mole fraction profiles were obtained through sonic probe sampling, and analyzed by gas chromatography and Fourier transform infrared spectrometry. As opposed to our previous studies on ethers (S. Thion et al. 2017, Z. Serinyel et al. 2018 and 2020), DIPE showed no low-temperature reactivity under the same experimental conditions. Oxidation of the rich mixture showed similarities to pyrolysis producing important quantities of propene and isopropanol, while no isopropanol is observed under lean conditions. In terms of overall reactivity, DIPE showed smaller fuel conversion compared to other symmetric ethers previously studied. The present data and literature experiments were simulated with our ether oxidation mechanism showing good agreement.& COPY; 2022 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

Automated summary

The oxidation of di-isopropyl-ether (DIPE) was investigated in a jet-stirred reactor under different fuel conditions. Mole fraction profiles were obtained and analyzed by gas chromatography and Fourier transform infrared spectrometry. Unlike previous studies on ethers, DIPE exhibited no low-temperature reactivity under the same experimental conditions. The oxidation of DIPE in rich mixture resembled pyrolysis, producing propene and isopropanol, while isopropanol was not observed under lean conditions. DIPE showed lower fuel conversion compared to other symmetric ethers previously studied, as confirmed by simulation with the ether oxidation mechanism.