Achieving high flame retardancy, crystallization and biodegradability PLA based on 1 wt% addition of novel fully bio-based flame retardant

In this paper, a bio-based flame retardant PA-AR is synthesized, which endows PLA with good flame retardant and crystallization properties, and at the same time promotes the biodegradability of PLA. Only 1 wt% PA-AR makes the LOI value of PLA reach 26.8% and reaches UL-94 V-0 level. In addition, 1 wt% PA-AR increases the crystallinity of PLA to 23.4%, which increased by 460% compared with PLA. Further, due to the increase of crystallinity, the tensile strength is also improved. Besides, the addition of PA-AR can greatly promote the degradation performance of PLA under specific biological conditions. This work proposed a novel method to obtain completely biodegradable flame retardant composites.

Automated summary

In this paper, a bio-based flame retardant PA-AR is synthesized, which endows PLA with good flame retardant and crystallization properties, and at the same time promotes the biodegradability of PLA. The addition of 1 wt% PA-AR significantly improves the LOI value, reaching UL-94 V-0 level, and increases the crystallinity and tensile strength of PLA. Moreover, PA-AR greatly enhances the degradation performance of PLA under specific biological conditions, providing a novel method to obtain completely biodegradable flame retardant composites.