期刊
POLYHEDRON
卷 223, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2022.115961
关键词
Hydroboration; Alkynes; Transition-metal-free; Borohydrides
资金
- National Science Centre, Poland (NCN) [UMO-2016/23/B/ST5/00177]
Sodium triethylborohydride is a commonly used catalyst that enables high selectivity in hydroboration reactions, with higher reactivity towards terminal alkynes.
Sodium triethylborohydride, a popular hydride transferring reagent, is commonly used as an activating agent for hydroboration catalysts based on the first-row transition metal complexes. It has been found that NaHBEt3 can be a selective catalyst for hydroboration of terminal alkynes with pinacolborane. Hydroboration of aromatic and aliphatic alkynes in the presence of 10 mol% of NaHBEt3 proceeded in a highly selective manner to give (E)-vinylboronate esters with high yields, whereas ethynylsilanes seem to be less reactive in this process. Internal alkynes can also be transformed into corresponding vinylboronate esters, however, this process require prolonged reaction times compared to their terminal counterparts.
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