☆ 4.5 Article

Structure and Reactivity of [Ru-Al] and [Ru-Sn] Heterobimetallic PPh3-Based Complexes

ORGANOMETALLICS (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Inorganic & Nuclear

Rational Preparation of Well-Defined Multinuclear Iridium-Aluminum Polyhydride Clusters and Comparative Reactivity

Leon Escomel et al.

Summary: We report a novel alkane elimination approach that involves the protonolysis of triisobutylaluminum by the acidic hydrides from Cp*IrH4. This strategy allows the synthesis of well-defined iridium aluminum polyhydride clusters with original structures and reactivities.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Versatile Fe-Sn Bonding Interactions in a Metallostannylene System: Multiple Bonding and C-H Bond Activation

Rex C. Handford et al.

Summary: The metallostannylene complex exhibits the formation of multiple bonds and the activation of phosphine ligands in both oxidation and reduction reactions. DFT studies suggest that the cleavage of C-H bonds across the Fe-Sn bond is favored over C-H activation exclusively at the tin center, highlighting the effect of iron-tin cooperativity in the system.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species

Debabrata Dhara et al.

Summary: This study reports the reduction of bulky ferrocenyl-based NHC-stabilised aluminium(iii) diiodide in different hydrocarbon solvents, with different outcomes observed in hexane and aromatic solvents. Reduction in hexane led to C-H activation, while reduction in aromatic solvents resulted in unknown Birch-type reductions of solvent molecules.

CHEMICAL SCIENCE (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Strongly Polarized Iridiumδ--Aluminumδ+ Pairs: Unconventional Reactivity Patterns Including CO2 Cooperative Reductive Cleavage

Leon Escomel et al.

Summary: The study demonstrates the formation of unusual iridium aluminum species through a reductive elimination route, showing strong polarized Al(III)-Ir(III) interactions. Reactivity studies further reveal that Lewis base binding to Al does not affect the reactivity of the Ir-Al motif, promoting cooperative reductive cleavage of various compounds.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Selective C-O Bond Reduction and Borylation of Aryl Ethers Catalyzed by a Rhodium-Aluminum Heterobimetallic Complex

Rin Seki et al.

Summary: In this study, we reported a novel rhodium catalyst with X-type PAlP pincer ligand for catalytic reduction of a C-O bond and borylation. The reaction mechanism was revealed through characterization of reaction intermediate and deuterium-labeling experiments. This catalytic system demonstrated steric-hindrance-dependent chemoselectivity, providing a new strategy for selective C-O bond activation through heterobimetallic catalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalysis using transition metal complexes featuring main group metal and metalloid compounds as supporting ligands

Jun Takaya

Summary: Recent research has demonstrated the promising utility of transition metal complexes with M-E bonds stabilized by multidentate ligands, where E represents a main group metal or metalloid element. Main group metal and metalloid ligands provide unique electronic and steric environments to transition metals, leading to remarkable catalytic activity and product selectivity. This perspective highlights the potential of these compounds as a new class of supporting ligands for transition metal catalysts in synthetic chemistry.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Zn-Promoted C-H Reductive Elimination and H2 Activation via a Dual Unsaturated Heterobimetallic Ru-Zn Intermediate

Fedor M. Miloserdov et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Unexpected Vulnerability of DPEphos to C-O Activation in the Presence of Nucleophilic Metal Hydrides

Mateusz K. Cybulski et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Impact of the Novel Z-Acceptor Ligand Bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the Formation and Reactivity of Low-Coordinate Ru(0) Centers

Fedor M. Miloserdov et al.

INORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Physical

Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand

Jun Takaya et al.

ACS CATALYSIS (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Bimetallic cooperation across the periodic table

Jesus Campos

NATURE REVIEWS CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bi- and tridentate stannylphosphines and their coordination to low-valent platinum

J. Jacobo Salazar-Diaz et al.

DALTON TRANSACTIONS (2019)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Highly efficient palladium-catalysed carbon dioxide hydrosilylation employing PMP ligands

Patrick Steinhoff et al.

DALTON TRANSACTIONS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

The partial dehydrogenation of aluminium dihydrides

Thomas N. Hooper et al.

CHEMICAL SCIENCE (2019)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Coordination chemistry of stannylene-based Lewis pairs - insertion into M-Cl and M-C bonds. From base stabilized stannylenes to bidentate ligands

K. M. Krebs et al.

DALTON TRANSACTIONS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Conceptual Extension of the Degradation-Transformation of N-Heterocyclic Carbenes: Unusual Rearrangements on Osmium

Miguel A. Esteruelas et al.

ORGANOMETALLICS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Tunable Binding of Dinitrogen to a Series of Heterobimetallic Hydride Complexes

Samantha Lau et al.

ORGANOMETALLICS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Tin(IV) Compounds with 2-C6F4PPh2 Substituents and Their Reactivity toward Palladium(0): Formation of Tin Palladium Complexes via Oxidative Addition

Erik Waechtler et al.

INORGANIC CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Phosphine-functionalized NHC Ni(II) and Ni(0) complexes: synthesis, characterization and catalytic properties

S. G. Rull et al.

DALTON TRANSACTIONS (2017)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Leveraging molecular metal-support interactions for H2 and N2 activation

Ryan C. Cammarota et al.

COORDINATION CHEMISTRY REVIEWS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals

Michael J. Butler et al.

CHEMICAL COMMUNICATIONS (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Complexes of ambiphilic ligands: reactivity and catalytic applications

Ghenwa Bouhadir et al.

CHEMICAL SOCIETY REVIEWS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Activation of H2 over the Ru-Zn Bond in the Transition Metal-Lewis Acid Heterobimetallic Species [Ru(IPr)2(CO)ZnEt]+

Ian M. Riddlestone et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Nickel-Triad Complexes of a Side-on Coordinating Distannene

Christian P. Sindlinger et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Synthesis of an [(NHC)2Pd(SiMe3)2] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes

Melvyn B. Ansell et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Interligand Interactions Dictate the Regioselectivity of trans-Hydrometalations and Related Reactions Catalyzed by [Cp*RuCl]. Hydrogen Bonding to a Chloride Ligand as a Steering Principle in Catalysis

Stephan M. Rummelt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of Mixed Silylene-Carbene Chelate Ligands from N-Heterocyclic Silylcarbenes Mediated by Nickel

Gengwen Tan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and Platinum Complexes of an Alane-Appended 1,1′-Bis(phosphino)ferrocene Ligand

Bradley E. Cowie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Ruthenium Hydrides Containing the Superhindered Polydentate Polyphosphine Ligand P(CH2CH2PtBu2)3

Ryan Gilbert-Wilson et al.

INORGANIC CHEMISTRY (2014)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Solid-State Structure and Solution Reactivity of [(Ph3P)4Ru(H)2] and Related Ru(II) Complexes Used in Catalysis: A Reinvestigation

Hamidreza Samouei et al.

ORGANOMETALLICS (2014)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

From AlCp- and GaCp-Ligated Ruthenium Hydrides to Zinc-Rich Heterometallic Complexes

Mariusz Molon et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bulky N-Phosphinomethyl-Functionalized N-Heterocyclic Carbene Chelate Ligands: Synthesis, Molecular Geometry, Electronic Structure, and Their Ruthenium Alkylidene Complexes

Hiyam Salem et al.

ORGANOMETALLICS (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A Tris(triphenylphosphine)aluminum Ambiphilic Precatalyst for the Reduction of Carbon Dioxide with Catecholborane

Marc-Andre Courtemanche et al.

ORGANOMETALLICS (2013)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Facile synthesis of rhodium and iridium complexes bearing a [PEP]-type ligand (E = Ge or Sn) via E-C bond cleavage

Hajime Kameo et al.

DALTON TRANSACTIONS (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

Effect of the Damping Function in Dispersion Corrected Density Functional Theory

Stefan Grimme et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2011)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Dehydrogenation of Hydridoirida-β-diketones in Methanol: The Selective Formation of Mono- and Dinuclear Acyl Complexes

Roberto Ciganda et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

Molecular Single-Bond Covalent Radii for Elements 1-118

Pekka Pyykko et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

添加到收藏夹

Software Review Chemistry, Multidisciplinary

OLEX2: a complete structure solution, refinement and analysis program

Oleg V. Dolomanov et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2009)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Covalent radii revisited

Beatriz Cordero et al.

DALTON TRANSACTIONS (2008)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A zwitterionic gold(I) complex from an ambiphilic diphosphino-alane ligand

Marie Sircoglou et al.

ORGANOMETALLICS (2008)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis and reactivity of platinum group metal complexes featuring the new pincer-like bis(phosphino)silyl ligand [κ3-(2-Ph2PC6H4)2SiMe]- ([PSiP]):: Application in the ruthenium-mediated transfer hydrogenation of ketones

Morgan C. MacInnis et al.

ORGANOMETALLICS (2007)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Snapshot of a chelation-assisted C-H/alkyne coupling:: A ruthenium complex caught in the act of C-C bond formation

Laure Benhamou et al.

ORGANOMETALLICS (2007)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Reaction of iron and ruthenium halogenide complexes with GaCp* and AlCp: Insertion, Cp transfer reactions and orthometallation

Beatrice Buchin et al.

INORGANICA CHIMICA ACTA (2006)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Similarities and contrasts between silyl and stannyl derivatives of ruthenium and osmium

Warren R. Roper et al.

ORGANOMETALLICS (2006)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Ortho-metallated transition metal complexes derived from tertiary phosphine and arsine ligands

Fabian Mohr et al.

COORDINATION CHEMISTRY REVIEWS (2006)

添加到收藏夹

Article Chemistry, Physical

Reaction of tetramethylimidazol-2-ylidene with (TptBu,Me)YbE(thf) (E=I, CH2SMe3):: simple adduct and a hydrocarbyl tethered carbene ligand

Gregory M. Ferrence et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2006)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A cyclic osmastannyl complex, Os(κ2(Sn,P)-SnMe2C6H4PPh2) (κ2-S2CNMe2(CO)(PPh3) derived from the osmastannol complex, Os(SnMe2OH)(κ2-S2CNMe2(CO)(PPh3)2

GL Lu et al.

INORGANICA CHIMICA ACTA (2005)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Metallacyclic complexes with ortho-stannylated triphenylphosphine ligands, LnOs(κ2(Sn,P)-SnMe2C6H4PPh2), derived from thermal reactions of the five-coordinate complex, Os(SnMe3)Cl(CO)(PPh3)2

GL Lu et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2005)

添加到收藏夹

Review Chemistry, Multidisciplinary

Quantum mechanical continuum solvation models

J Tomasi et al.

CHEMICAL REVIEWS (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and reactivity of silyl ruthenium complexes: The importance of trans effects in C-H activation, Si-C bond formation, and dehydrogenative coupling of silanes

VK Dioumaev et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

One-pot synthesis of (η6-arene)bis(triphenylphosphine)(methyl)ruthenium(II) cations.: X-ray structures of [(η6-C6H6)Ru(Me)(PPh3)2]-[AlCl2Me2] and the η5-thiophene analogue

XG Fang et al.

ORGANOMETALLICS (2002)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Cyclometallated complexes of ruthenium and osmium containing the o-C6H4PPh2 ligand

MA Bennett et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2000)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Complexes of platinum(II), platinum(IV), rhodium(III) and iridium(III) containing orthometallated triphenylphosphine

MA Bennett et al.

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.