期刊
ORGANIC LETTERS
卷 24, 期 41, 页码 7544-7548出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c02889
关键词
-
资金
- Fluorine 19 Fund
- National Science Foundation MRI program [1919565]
A novel method for accessing energetic salts based on [1,2,5]oxadiazolo[3,4-d]pyrimidine and three alkali metals, sodium, potassium, and cesium, was developed. The compounds exhibited high thermal stability, high density, good detonation properties, and insensitivity, suggesting potential applications in heat-resistant explosives.
A novel method for accessing energetic salts of a fused-ring skeleton based on [1,2,5]oxadiazolo[3,4-d]pyrimidine and three alkali metals, sodium (Na), potassium (K), and cesium (Cs), was developed. All three compounds were fully characterized, and their structures were confirmed by single-crystal X-ray analysis. They were highly thermally stable (>290 degrees C) and had high density, good detonation properties, and insensitive properties, which suggested possible heat-resistant explosive applications.
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