期刊
ORGANIC LETTERS
卷 24, 期 35, 页码 6417-6422出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c02494
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资金
- Department of Energy of USA [DE-SC0020260]
- U.S. Department of Energy (DOE) [DE-SC0020260] Funding Source: U.S. Department of Energy (DOE)
This study reports the oxidative [4 + 2] reaction of o-phenylenediamine-derived disulfonamides with fullerene C-60 and C-70. The reactants with electron deficiency showed high reactivity. The reaction of C-70 exhibited unusual regioselectivity, yielding a [5,6]-adduct as the major product, which was characterized by experimental and computational methods.
The oxidative [4 + 2] reaction of o-phenylenedi-amine-derived disulfonamides with fullerene C-60 and C-70 is reported, in which electron-deficient reactants showed high reactivity. The reaction of C-70 exhibited unusual regioselectivity, yielding a [5,6]-adduct as the major product, which was characterized by( 1)H, C-13 NMR and single-crystal X-ray diffraction. DFT calculations revealed the reaction is an inverse-electron demand Diels-Alder (IEDDA) reaction, and the [5,6]-adduct of C-70 is a kinetic product.
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