期刊
CARBOHYDRATE RESEARCH
卷 408, 期 -, 页码 51-95出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carres.2015.02.007
关键词
By-products; Hydrolysis; Elimination; Thioglycosides; Trichloroacetimidates
资金
- Villum Foundation, Denmark
- Villum Fonden [00007259] Funding Source: researchfish
Chemical glycosylation is central to carbohydrate chemistry and is generally recognised as a challenging reaction. This review describes the most reoccurring side reactions of glycosyl donors in glycosylation and how scientists have attempted to explain their observations and in some cases succeeded in solving a particular encountered problem. The topics covered are donor hydrolysis, elimination to form glycals, intermolecular aglycon transfer of thioglycosides and glycosyl imidate rearrangement. (C) 2015 Elsevier Ltd. All rights reserved.
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