期刊
OPTICS AND LASER TECHNOLOGY
卷 155, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.optlastec.2022.108347
关键词
NacaTiTaO(6):Dy3+; Double perovskite; Thermal stability; LEDs
资金
- Natural Science Foundation of Shaanxi Province [2022NY-224]
- Undergraduate Innovation Fund of Northwest A&F University, China [202110712190, 202110712188, S202110712707, S202010712314, S202010712006]
- Guangzhou Science and Technology Project [202102080326]
- Home for researchers, China
A new yellow-emitting phosphor, NaCaTiTaO6:Dy3+, with a stable double perovskite structure, was successfully synthesized via solid-phase synthesis. The phosphor showed a particle size of approximately 3.8 μm and exhibited a maximum emission peak at 574 nm under irradiation at 389 nm. The Dy3+ doping concentration was optimized and the phosphor demonstrated high thermal stability. Its excellent luminescence properties make it suitable for application in white-light emitting diodes (w-LEDs).
A new yellow-emitting phosphor, NaCaTiTaO6:Dy3+, was synthesized via solid-phase synthesis at 1300 degrees C. X-ray diffraction (XRD) analysis and Rietveld refinement showed that the prepared phosphors exhibited a stable double perovskite structure. The particle size of the phosphor was around 3.8 mu m. The maximum emission peak at 574 nm is attributed to the F-4(9/2)-> H-6(13/2) energy level transition under irradiation at 389 nm. The optimum Dy3+ doping concentration is 0.10 M equivalent, and concentration quenching is due to the nearest neighbor ion interaction. The luminescence intensity of the phosphor was reduced by only 15% at 420 K, exhibiting high thermal stability. Quantum yield (QY) was measured to be 26.31%. Finally, the Commission International de I'Eclairage (CIE) color coordinate of the phosphor for white light emitting diode (w-LED) was (0.314, 0.323), with a color rendering index (R-a) of 92 and a correlated color temperature (CCT) of 5578 K. Above all, the Dy3+-doped double perovskite NaCaTiTaO6:Dy3+ phosphor is expected to be used in w-LEDs.
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