Spectroscopic characterizations of Dy3+ ions doped phosphate glasses for epoxy-free white LED applications

The present work illustrates a detailed spectroscopic analysis carried out on dysprosium ions doped Zinc Alumino Sodium Phosphate (ZnAlNaP) glasses with chemical composition of (10-x)ZnO-20Al(2)O(3)-10Na(2)O-60P(2)O(5)-xDy(2)O(3) (x = 0.1-2.0 mol%). The XRD spectra verified for an un-doped and Dy3+ ions doped ZnAlNaP glasses demonstrate an enormous hump confirming its amorphous behavior. The FT-IR and Raman spectrum recorded for an un-doped ZnAlNaP and ZnAlNaPDy1.0 glass elucidates various functional groups and vibrational modes involved, respectively. The DSC & TGA studies conducted on an un-doped ZnAlNaP glass revealed its thermal stability and overall weight loss. The absorption spectra were used to calculate the optical bandgap for the as-synthesized glasses and were found to be in the range of 2.9 eV-4.7 eV. Photoluminescence (PL) excitation, emission and decay spectral analysis were done to investigate the suitability of the as-synthesized glasses for epoxy-free solid-state lighting (SSL) devices. The PL emission recorded under 350 nm excitation show two significant bands in blue and yellow regions. Temperature-dependent PL studies conducted on ZnAlNaPDy1.0 glass revealed activation energy of 0.212 eV with a 25.6% loss in PL intensity. The CIE color chromaticity coordinates and correlated color temperature (CCT) were calculated from the PL spectral characteristics. All the spectroscopic investigations conducted on the as-synthesized ZnAlNaPDy glasses finally reveal their superior nature for fabricating epoxy-free white-light emitting diodes (w-LEDs).

Automated summary

This study presents a detailed spectroscopic analysis of dysprosium ions doped ZnAlNaP glasses, demonstrating their potential for epoxy-free white-light emitting diodes (w-LEDs).